Reactions of Ethyl-3-pentenoate with all given reagents are given below.
Reaction with H₂ / Pd: The non-polar double bond present in Ethyl-3-pentenoate is reduced to saturated chain. This reagent can not reduce the carbonyl group.
Reaction with NaBH₄: Sodium Borohydride is a weak reducing agent at compared to LiAlH₄. It can only reduce aldehydes and Ketones to corresponding alcohols.
Reaction with LiAlH₄: Lithium Aluminium hydride is a strong reducing agent. It can reduce all types of carbonyl compounds to corresponding alcohols, But, it can not reduce non-polar double bonds like alkenes and alkynes.
Result: The correct answer is Option-A (Highlighted RED below).