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Serga [27]
3 years ago
10

in order to find the molar mass of an unknown compound, a research scientist prepared a solution of 0.930 g of an unknown in 125

g of a solvent. The pure solvent had a freezing point of 74.2 degrees celcius, and the solution had a freezing point of 73.4 degrees celcius. Given the solvents freezing point depreesion contant, Kf=5.50 degrees celcius/m, find the molar mass of the unknown
Chemistry
1 answer:
PtichkaEL [24]3 years ago
3 0

Answer:

Molar mass→ 0.930 g / 6.45×10⁻³ mol = 144.15 g/mol

Explanation:

Let's apply the formula for freezing point depression:

ΔT = Kf . m

ΔT = 74.2°C - 73.4°C → 0.8°C

Difference between the freezing T° of pure solvent and freezing T° of solution

Kf = Cryoscopic constant → 5.5°C/m

So, if we replace in the formula

ΔT = Kf . m → ΔT / Kf = m

0.8°C / 5.5 m/°C = m → 0.0516 mol/kg

These are the moles in 1 kg of solvent so let's find out the moles in our mass of solvent which is 0.125 kg

0.0516 mol/kg . 0.125 kg = 6.45×10⁻³ moles. Now we can determine the molar mass:

Molar mass (mol/kg) → 0.930 g / 6.45×10⁻³ mol = 144.15 g/mol

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Answer is: dipole-induced dipole interactions.

Intermolecular forces are the forces between molecules or particles.

There are several types of intermolecular forces: hydrogen bonding, ion-induced dipole forces, ion-dipole forces and van der Waals forces.

A dipole-induced dipole interaction is a weak attraction that results when a polar molecule induces a dipole in a nonpolar molecule by disturbing the arrangement of electrons in the nonpolar species.

4 0
3 years ago
Read 2 more answers
A 150.0 mL solution of 2.888 M strontium nitrate is mixed with 200.0 mL of a 3.076 M sodium fluoride solution. Calculate the mas
Lelechka [254]

Answer:

Mass SrF2 produced = 38.63 g SrF2 produced

[Na^+]:  = 1.758 M

[NO3^-]:  = 1.238 M

[Sr^2+] = 0.3589 M

[F^-] = 2.36*10^-5 M

Explanation:

Step 1: Data given

Volume of 2.888M strontium nitrate = 150.0 mL = 0.150 L

Volume of 3.076 M sodium fluoride = 200.0 mL = 0.200 L

Step 2 : The balanced equation

Sr(NO3)2(aq) + 2NaF(aq) → SrF2(s) + 2NaNO3(aq) → Sr2+ + 2F- + 2

Step 3: Calculate moles strontium nitrate

Moles Sr(NO3)2 = Molarity * volume  

Moles Sr(NO3)2 = 2.888 M * 0.150 L

Moles Sr(NO3)2 = 0.4332 moles

Step 4: Calculate moles NaF

Moles NaF = 3.076 M * 0.200 L

Moles NaF = 0.6152 moles

It takes 2 moles F^- to precipitate 1 mole Sr^2+, so F^- is limiting.

Step 5: Calculate limiting reactant

For 1 mol of Sr(NO3)2 we need 2 moles of NaF to produce 1 mol of SrF2 and 2 moles of NaNO3

NaF is the limiting reactant. It will completely be consumed (0.6152 moles).

Sr(NO3)2 is in excess. There will react 0.6152/2 = 0.3076 moles

Moles Sr^2+ precipitated by F^- = 0.3076

There will remain 0.4332 - 0.3076 = 0.1256 moles of Sr(NO3)2

Moles Sr^2+ no precipitated (left over) = 0.1256 moles

Step 6: Calculate moles SrF2  

For 1 mol of Sr(NO3)2 we need 2 moles of NaF to produce 1 mol of SrF2 and 2 moles of NaNO3

For 0.6152 moles NaF we have 0.6152/2 = 0.3076 moles of SrF2

Mass SrF2 produced:  0.3076 mol * 125.6 g/mol = 38.63 g SrF2 produced

Step 7: Calculate concentration of [Na+] and [NO3-]

Since both Na^+ and NO3^- are spectator ions, and the final volume is 150 ml + 200 ml = 350 ml (0.350 L), the concentrations of Na^+ and NO3^- can be calculated as follows:

[Na^+]:  (200 ml)(3.076 M) = (350 ml)(x M) and x = 1.758 M

[NO3^-]:  (150 ml)(2.888 M)(2) = (350 ml)(x M) = 1.238 M

Step 8: Calculate [Sr^2+] and [F^-]

[Sr^2+] = 0.1256 moles/0.350 L = 0.3589 M

To find [F^-], one needs the Ksp for SrF2.  There are several values listed in the literature. I am using a value of 2x10^-10.

SrF2(s) <==> Sr^2+(aq) + 2F^-(aq)

Ksp = [Sr^2+][F^-]²

2x10^-10 = (0.3589)(x)²

x² = 5.57*10^-10

x = [F^-] = 2.36*10^-5 M

4 0
3 years ago
How many carbon atoms are present in 0.46 moles of C2H6O?
s2008m [1.1K]
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Number of atoms in 0.46 mole = 0.46 * 6.023 * 10²³
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In short, Your Answer would be Option B

Hope this helps!
3 0
3 years ago
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Indicate which of the following criteria are important for the selection of a buffer to use in an in vitro biochemical reaction.
JulsSmile [24]

Answer:

The correct answer is: d. The pKa of the chosen buffer should be close to the optimal pH for the biochemical reaction.

Explanation:

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Thus it is important to select a buffer with pKa close to the optimum pH of the reaction because the ability for the buffer to maintain the pH is is great at the pH close to pKa.

7 0
3 years ago
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