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From the value Kf=1.2×109 for Ni(NH3)62+, calculate the concentration of NH3 required to just dissolve 0.016 mol of NiC2O4 (Ksp

Nina [5.8K]

Answer: The concentration of $NH_3$ required will be 0.285 M.

Explanation:

To calculate the molarity of $NiC_2O_4$ , we use the equation:

$\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}$

Moles of $NiC_2O_4$ = 0.016 moles

Volume of solution = 1 L

Putting values in above equation, we get:

$\text{Molarity of }NiC_2O_4=\frac{0.016mol}{1L}=0.016M$

For the given chemical equations:

$NiC_2O_4(s)\rightleftharpoons Ni^{2+}(aq.)+C_2O_4^{2-}(aq.);K_{sp}=4.0\times 10^{-10}$

$Ni^{2+}(aq.)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K_f=1.2\times 10^9$

Net equation: $NiC_2O_4(s)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K=?$

To calculate the equilibrium constant, K for above equation, we get:

$K=K_{sp}\times K_f\\K=(4.0\times 10^{-10})\times (1.2\times 10^9)=0.48$

The expression for equilibrium constant of above equation is:

$K=\frac{[C_2O_4^{2-}][[Ni(NH_3)_6]^{2+}]}{[NiC_2O_4][NH_3]^6}$

As, $NiC_2O_4$ is a solid, so its activity is taken as 1 and so for $C_2O_4^{2-}$

We are given:

$[[Ni(NH_3)_6]^{2+}]=0.016M$

Putting values in above equations, we get:

$0.48=\frac{0.016}{[NH_3]^6}}$

$[NH_3]=0.285M$

Hence, the concentration of $NH_3$ required will be 0.285 M.

7 0

3 years ago

What mass of copper sulphate dissolves in 100g of water at 70 °C

ValentinkaMS [17]

The answer mass of copper sulphate is

46g

6 0

3 years ago

How does the average velocity of molecules in a high-temperature gas compare to the average velocity of molecules of the same ga

IrinaK [193]

Answer:lower temp molecules act slower so they come closer together and heated molecules are more spaced out that is why when you put an ice cube in a hot pan the ice melts and turns into a liquid due to heat the molecules space out

Explanation:

8 0

3 years ago

Can you guys help me please!!!!

Masteriza [31]

Answer:

i think it is true

Explanation:

if it correct plz plz mark as brainliest

thank you

19NBoli

4 0

3 years ago

Read 2 more answers

1.00g of a metallic element reacts completely with 300cm3 of oxygen at 298K and 1 atm pressure to form an oxide which contains O

elena55 [62]

Answer:

The metal is most likely calcium which has a molar mass of 40.078 g

Note: The question is incomplete. The complete question is given below:

1.00g of a metallic element reacts completely with 300cm3 of oxygen at 298K and 1 atm pressure to form an oxide which contains O2– ions. The volume of one mole of gas at this temperature and pressure is 24.0dm3 .

What could be the identity of the metal?

A calcium B magnesium C potassium D sodium

Explanation:

Number of moles of the oxygen gas reacted is first determined:

Volume of oxygen gas = 300 cm³ = 0.30 dm³

1 mole of a gas occupies 24.0 dm³ at this temperature and pressure

Number of moles of oxygen gas that will occupy 0.30 dm³ = 0.3/24 = 0.125 moles

Let M be represent the metallic element. The equation of the reaction will be:

2M + O₂ ----> 2MO

From the equation of reaction;

2 moles of the metal reacts with 1 mole of oxygen gas

2 * 0.125 moles of the metal will react with 300 cm³ of oxygen = 0.025 moles

Since the mass of the metal that reacted with oxygen is 1.0 g, therefore, 1.0 g of the metal = 0.025 moles

mass of 1 mole of the metal = 1 /0.025 = 40.0 g

Therefore, the metal is most likely calcium which has a molar mass of 40.078 g

5 0

3 years ago