For this, we use equations from the colligative properties of solutions specifically boiling point elevation and freezing point depression. The equations for these are expressed as:
ΔTb = kb m
where k is a boiling point elevation constant and m is the concentration in terms of molality
ΔTf = kf m
where k is a freezing point elevation <span>constant and m is the concentration in terms of molality
</span>
We use both expression to solve for the freezing point. For this case, concentration is the same. The equation will then be:
ΔTf = kf ( ΔTb / kb )
0-Tf = 1.86 (103.7 - 100 / 0.512 )
Tf = -13.4°C
Initial Conditions:
Volume=v1= 3.5 L
Temperature= T1 =298K
Final Conditions:
Temperature= T2= 285K
Volume= v2= ?
Use the general gas equation;
P1*v1/T1 = P2*v2/T2
Note:
Pressure is constant
so the equation become,
v1/T1 = v2/T2
3.5/298 = v2/285
v2 = 3.347 L
Isomers have same formula but the different
arrangement of atoms/ structure.
<span>Butane is an alkane which has 4 carbon atoms.
The formula is C4H10. 2-methyl propane is also an alkane which has 4 carbon
atoms. The formula is also C4H10. Only difference in these compounds is 2-methyl
propane has 3 carbon atoms in main carbon chain and there is CH3- group in 2nd
C atom while butane has 4 carbon atoms in main carbon chain. </span>
<span>The structures are as the image.</span>
<span>
</span>
C,H and O are present in monosaccharides