When ketone is reacted with phosphorous pentachloride, chlorination takes place at the carbonyl carbon with substitution of the oxygen atom to give a geminal dichloride (with 2 Cl atoms on same carbon) according to the following equation:
so we can say that acetone is converted into 2,2-dichloropropane by action of PCl₅
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Answer:
Explanation:
cM 0 0
So dissociation constant will be:
Given: c = 0.15 M
pH = 1.86
= ?
Putting in the values we get:
Also
As
Thus the vale of for the acid is
Answer: Option (b) is the correct answer.
Explanation:
In a chemical reaction, the bonds between the reactant molecules tend to break leading to the formation of new bonds to produce products.
So, in order to break the bonds between the reactant molecules, energy is required to overcome the attraction between the atoms.
To form new bonds, energy gets released when two atoms come closer to each other. Hence, formation of bond releases energy.
As in the given reaction it is shown that < 0, that is, enthalpy change is negative. Hence, energy is released as it is an exothermic process.
Thus, we can conclude that the statement energy released as the bonds in the reactants is broken is greater than the energy absorbed as the bonds in the products are formed, is true about the bond energies in this reaction.