The probability that the first volunteer is a man would be 32/52, since there are 32 men out of 52 people. The probability that the second volunteer would also be a man would be 31/51, since there is 1 fewer man and 1 fewer person total to choose from.
if you subtract a negative number, it’s the same as adding a positive number. If you add 2 positive numbers, you get a positive number, so the expression is positive.