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3 years ago

8

What do chemists study

2 answers:

Contact [7]3 years ago

5 0

Answer: Chemist study properties of matter at the level of atoms and molecules. They measure proportions and reaction rate in order to see how unfamiliar substance and how they behave

Explanation:

ANTONII [103]3 years ago

3 0

Answer:

Chemists investigate the properties of matter at the level of atoms and molecules. They measure proportions and reaction rates in order to understand unfamiliar substances and how they behave, or to create new compounds for use in a variety of practical applications.

Explanation:

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3 years ago

. Determine the standard free energy change, ɔ(G p for the formation of S2−(aq) given that the ɔ(G p for Ag+(aq) and Ag2S(s) are

olga nikolaevna [1]

<u>Answer:</u> The standard free energy change of formation of $S^{2-}(aq.)$ is 92.094 kJ/mol

<u>Explanation:</u>

We are given:

$K_{sp}\text{ of }Ag_2S=8\times 10^{-51}$

Relation between standard Gibbs free energy and equilibrium constant follows:

$\Delta G^o=-RT\ln K$

where,

$\Delta G^o$ = standard Gibbs free energy = ?

R = Gas constant = $8.314J/K mol$

T = temperature = $25^oC=[273+25]K=298K$

K = equilibrium constant or solubility product = $8\times 10^{-51}$

Putting values in above equation, we get:

$\Delta G^o=-(8.314J/K.mol)\times 298K\times \ln (8\times 10^{-51})\\\\\Delta G^o=285793.9J/mol=285.794kJ$

For the given chemical equation:

$Ag_2S(s)\rightleftharpoons 2Ag^+(aq.)+S^{2-}(aq.)$

The equation used to calculate Gibbs free change is of a reaction is:

$\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]$

The equation for the Gibbs free energy change of the above reaction is:

$\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]$

We are given:

$\Delta G^o_f_{(Ag_2S(s))}=-39.5kJ/mol\\\Delta G^o_f_{(Ag^+(aq.))}=77.1kJ/mol\\\Delta G^o=285.794kJ$

Putting values in above equation, we get:

$285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol$

Hence, the standard free energy change of formation of $S^{2-}(aq.)$ is 92.094 kJ/mol

8 0

3 years ago