<u>Answer:</u> The molality of the solution is 0.11 m
<u>Explanation:</u>
We are given:
Mole fraction of methanol = 0.135
This means that 0.135 moles of methanol is present in 1 mole of a solution
Moles of ethanol = 1 - 0.135 = 0.865 moles
To calculate the mass for given number of moles, we use the equation:
![\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}](https://tex.z-dn.net/?f=%5Ctext%7BNumber%20of%20moles%7D%3D%5Cfrac%7B%5Ctext%7BGiven%20mass%7D%7D%7B%5Ctext%7BMolar%20mass%7D%7D)
Moles of ethanol = 0.865 moles
Molar mass of ethanol = 46 g/mol
![0.865mol=\frac{\text{Mass of ethanol}}{46g/mol}\\\\\text{Mass of ethanol}=(0.865mol\times 46g/mol}=39.79g](https://tex.z-dn.net/?f=0.865mol%3D%5Cfrac%7B%5Ctext%7BMass%20of%20ethanol%7D%7D%7B46g%2Fmol%7D%5C%5C%5C%5C%5Ctext%7BMass%20of%20ethanol%7D%3D%280.865mol%5Ctimes%2046g%2Fmol%7D%3D39.79g)
To calculate the molality of solution, we use the equation:
![Molality=\frac{m_{solute}\times 1000}{M_{solute}\times W_{solvent}\text{ (in grams)}}](https://tex.z-dn.net/?f=Molality%3D%5Cfrac%7Bm_%7Bsolute%7D%5Ctimes%201000%7D%7BM_%7Bsolute%7D%5Ctimes%20W_%7Bsolvent%7D%5Ctext%7B%20%28in%20grams%29%7D%7D)
Where,
= Given mass of solute (methanol) = 0.135 g
= Molar mass of solute (methanol) = 32 g/mol
= Mass of solvent (ethanol) = 39.79 g
Putting values in above equation, we get:
![\text{Molality of methanol}=\frac{0.135\times 1000}{32\times 39.79}\\\\\text{Molality of methanol}=0.106m\approx 0.11m](https://tex.z-dn.net/?f=%5Ctext%7BMolality%20of%20methanol%7D%3D%5Cfrac%7B0.135%5Ctimes%201000%7D%7B32%5Ctimes%2039.79%7D%5C%5C%5C%5C%5Ctext%7BMolality%20of%20methanol%7D%3D0.106m%5Capprox%200.11m)
Hence, the molality of the solution is 0.11 m