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natima [27]
3 years ago
11

Complete and balance the molecular equation for the reaction of aqueous sodium carbonate, Na 2 CO 3 Na2CO3 , and aqueous nickel(

II) chloride, NiCl 2 NiCl2 . Include physical states. molecular equation:
Na 2 CO 3 ( aq ) + NiCl 2 ( aq ) ⟶ 2 NaCl ( aq ) + NiCO 3 ( s ) Na2CO3(aq)+NiCl2(aq)⟶2NaCl(aq)+NiCO3(s) Enter the balanced net ionic equation for this reaction. Include physical states. net ionic equation:
Chemistry
1 answer:
antoniya [11.8K]3 years ago
3 0

<u>Answer:</u> The net ionic equation is written below.

<u>Explanation:</u>

Net ionic equation of any reaction does not include any spectator ions.

Spectator ions are defined as the ions which does not get involved in a chemical equation. They are found on both the sides of the chemical reaction when it is present in ionic form.

The chemical equation for the reaction of sodium carbonate and nickel (II) chloride is given as:

Na_2CO_3(aq.)+NiCl_2(aq.)\rightarrow 2NaCl(aq.)+NiCO_3(s)

Ionic form of the above equation follows:

2Na^{+}(aq.)+CO_3^{2-}(aq.)+Ni^{2+}(aq.)+2Cl^{-}(aq.)\rightarrow NiCO_3(s)+2Na^+(aq.)+2Cl^-(aq.)

As, sodium and chloride ions are present on both the sides of the reaction. Thus, it will not be present in the net ionic equation and are spectator ions.

The net ionic equation for the above reaction follows:

Ni^{2+}(aq.)+CO_3^{2-}(aq.)\rightarrow NiCO_3(s)

Hence, the net ionic equation is written above.

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When 2.00 g of methane are burned in a bomb calorimeter, the change in temperature is 3.08°C. The heat capacity of the calorimet
melisa1 [442]

Answer:

The approximate molar enthalpy of combustion of this substance is -66 kJ/mole.

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Now we have to calculate molar enthalpy of combustion of this substance :

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Considering the Hess's Law, the enthalpy change for the reaction is 221.8 kJ/mol.

Hess's Law indicates that the enthalpy change in a chemical reaction will be the same whether it occurs in a single stage or in several stages. That is, the sum of the ∆H of each stage of the reaction will give us a value equal to the ∆H of the reaction when it occurs in a single stage.

In this case you want to calculate the enthalpy change of:

C₂H₄ (g) + 6 F₂ (g) → 2 CF₄ (g) + 4 HF (g)

which occurs in three stages.

You know the following reactions, with their corresponding enthalpies:

Equation 1: H₂ (g) + F₂ (g) → 2 HF (g)     ∆H° = -79.2 kJ/mol

Equation 2: C (s) + 2 F₂ (g) → CF₄ (g)     ∆H° = 141.3 kJ/mol

Equation 3: 2 C(s) + 2 H₂ (g) → C₂H₄ (g)     ∆H° = -97.6 kJ/mol

Because of the way formation reactions are defined, any chemical reaction can be written as a combination of formation reactions, some going forward and some going back.

<h3 /><h3>FIRST STEP</h3>

First, to obtain the enthalpy of the desired chemical reaction you need one mole of C₂H₄ (g) on reactant side and it is present in first equation. Since this equation has one mole of C₂H₄ (g) on the product side, it is necessary to locate it on the reactant side (invert it).

When an equation is inverted, the sign of ΔH° also changes.

<h3>SECOND STEP</h3>

Now, you need 2 moles of CF₄ (g) on the product side. The second equation has 1 mole of CF₄ (g) on the product side, so it is necessary to multiply it by 2 to obtain 2 moles of CF₄ (g).

Since enthalpy is an extensive property, that is, it depends on the amount of matter present, since the equation is multiply by 2, the variation of enthalpy also.

<h3>THIRD STEP</h3>

Finally, you need 4 moles of  HF (g) on the product side. The first equation has 2 moles of  HF (g) on the product side, so it is necessary to multiply it by 2 to obtain 4 moles of the compound.

Since the equation is multiply by 2, the variation of enthalpy also is multiplied by 2.

<h3>SUMMARY</h3>

In summary, you know that three equations with their corresponding enthalpies are:

Equation 1: 2 H₂ (g) + 2 F₂ (g) → 4 HF (g)     ∆H° = -158.4 kJ/mol

Equation 2: 2 C (s) + 4 F₂ (g) → 2 CF₄ (g)     ∆H° = 282.6 kJ/mol

Equation 3: C₂H₄ (g) → 2 C(s) + 2 H₂ (g)     ∆H° = 97.6 kJ/mol

Adding or canceling the reactants and products as appropriate, and adding the enthalpies algebraically, you obtain:

C₂H₄ (g) + 6 F₂ (g) → 2 CF₄ (g) + 4 HF (g)     ΔH°= 221.8 kJ/mol

Finally, the enthalpy change for the reaction is 221.8 kJ/mol.

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