In an unknown liquid, the percentage composition with respect to carbon, hydrogen and iodine is 34.31%, 5.28% and 60.41% respectively.
Let the mass of liquid be 100 g thus, mass of carbon, hydrogen and oxygen will be 34.31 g, 5.28 g and 60.41 g respectively.
To calculate molecular formula of compound, convert mass into number of moles as follows:

Molar mass of carbon, hydrogen and iodine is 12 g/mol, 1 g/mol and 126.90 g/mol.
Taking the ratio:

Putting the values,

Thus, molecular formula of compound will be
.
Answer:
2269.43 mL
Explanation:
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Solution is here,
for initial case,
temperature(T1)=70°C=70+ 273=343K
vloume( V1) =45 L
for final case,
temperature( T2)=?
volume(V2)= 91.3 L
at constant pressure,
V1/V2 = T1/T2
or, 45/91.3 = 343/ T2
or, T2= (343×91.3)/45
or, T2=695.9 K = (695.9-273)°C=422.9°C