<u>Answer:</u> The enthalpy change of the reaction is 58 kJ.
<u>Explanation:</u>
Enthalpy change is defined as the difference in enthalpies of all the product and the reactants each multiplied with their respective number of moles. It is represented as
The equation used to calculate enthalpy change is of a reaction is:
For the given chemical reaction:
The equation for the enthalpy change of the above reaction is:
We are given:
Putting values in above equation, we get:
Hence, the enthalpy change of the reaction is 58 kJ.
The tert-butyl chloride in ethanol would surely react faster than the solvolysis of 1-chloro-2,2-dimethyl propane. It is known that both reactions are under the SN2 category so it would be hard for these reactions to occur. However, SN1 reactions are possible because of the ethanol which is a polar solvent. Both would form carbocations but tert-butyl chloride forms a more stable carbocation while the 1-chloro-2,2-dimethyl propane forms a primary carbocation only.
Answer:
The effects of supercritical CO2 (SC-CO2) on the microbiological, sensory (taste, odour, and colour), nutritional (vitamin C content), and physical (cloud, total acidity, pH, and °Brix) qualities of orange juice were studied. The CO2 treatment was performed in a 1 litre capacity double-walled reactor equipped with a magnetic stirring system. Freshly extracted orange juice was treated with supercritical CO2, pasteurised at 90°C, or left untreated. There were no significant differences in the sensory attributes and physical qualities between the CO2 treated juice and freshly extracted juice. The CO2 treated juice retained 88% of its vitamin C, while the pasteurised juice was notably different from the fresh juice and preserved only 57% of its vitamin C content. After 8 weeks of storage at 4°C, there was no microbial growth in the CO2 treated juice.
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