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ale4655 [162]
4 years ago
8

Indicate which reaction will occur faster. explain your reasoning. select the single best answer. solvolysis of 1−chloro−2,2−dim

ethylpropane or tert−butyl chloride in ethanol
Chemistry
1 answer:
Radda [10]4 years ago
6 0
The tert-butyl chloride in ethanol would surely react faster than the solvolysis of 1-chloro-2,2-dimethyl propane. It is known that both reactions are under the SN2 category so it would be hard for these reactions to occur. However, SN1 reactions are possible because of the ethanol which is a polar solvent. Both would form carbocations but tert-butyl chloride forms a more stable carbocation while the 1-chloro-2,2-dimethyl propane forms a primary carbocation only. 
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As we move down the group atomic radii increased with increase of atomic number. The addition of electron in next level cause the atomic radii to increased. The hold of nucleus on valance shell become weaker because of shielding of electrons thus size of atom increased. The electron affinity decreases because of shielding effect and thus atom become less reactive.

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