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rodikova [14]
4 years ago
10

Antimony has two naturally occuring isotopes, 121 Sb and 123 Sb . 121 Sb has an atomic mass of 120.9038 u , and 123 Sb has an at

omic mass of 122.9042 u . Antimony has an average atomic mass of 121.7601 u . What is the percent natural abundance of each isotope?
Chemistry
1 answer:
valina [46]4 years ago
6 0

Answer:

Percentage abundance of 121 Sb is = 57.2 %

Percentage abundance of 123 Sb is = 42.8 %

Explanation:

The formula for the calculation of the average atomic mass is:

Average\ atomic\ mass=(\frac {\%\ of\ the\ first\ isotope}{100}\times {Mass\ of\ the\ first\ isotope})+(\frac {\%\ of\ the\ second\ isotope}{100}\times {Mass\ of\ the\ second\ isotope})

Given that:

Since the element has only 2 isotopes, so the let the percentage of first be x and the second is 100 -x.

For first isotope, 121 Sb :

% = x %

Mass = 120.9038 u

For second isotope, 123 Sb:

% = 100  - x  

Mass = 122.9042 u

Given, Average Mass = 121.7601 u

Thus,  

121.7601=\frac{x}{100}\times 120.9038+\frac{100-x}{100}\times 122.9042

120.9038x+122.9042\left(100-x\right)=12176.01

Solving for x, we get that:

x = 57.2 %

<u>Thus, percentage abundance of 121 Sb is = 57.2 % </u>

<u>percentage abundance of 123 Sb is = 100 - 57.2 %  = 42.8 %</u>

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A solution was prepared by dissolving 195.0 g of KCl in 215 g of water. Calculate the mole fraction of KCl. (The formula weight
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Answer:

Approximately 0.180.

Explanation:

The mole fraction of a compound in a solution is:

\displaystyle \frac{\text{Number of moles of compound in question}}{\text{Number of moles of all particles in the solution}}.

In this question, the mole fraction of \rm KCl in this solution would be:

\displaystyle X_\mathrm{KCl} = \frac{n(\mathrm{KCl})}{n(\text{All particles in this soluton})}.

This solution consist of only \rm KCl and water (i.e., \rm H_2O.) Hence:

\begin{aligned} X_\mathrm{KCl} &= \frac{n(\mathrm{KCl})}{n(\text{All particles in this soluton})}\\ &= \frac{n(\mathrm{KCl})}{n(\mathrm{KCl}) + n(\mathrm{H_2O})}\end{aligned}.

From the question:

  • Mass of \rm KCl: m(\mathrm{KCl}) = 195.0\; \rm g.
  • Molar mass of \rm KCl: M(\mathrm{KCl}) = 74.6\; \rm g \cdot mol^{-1}.
  • Mass of \rm H_2O: m(\mathrm{H_2O}) = 215\; \rm g.
  • Molar mass of \rm H_2O: M(\mathrm{H_2O}) = 18.0\; \rm g\cdot mol^{-1}.

Apply the formula \displaystyle n = \frac{m}{M} to find the number of moles of \rm KCl and \rm H_2O in this solution.

\begin{aligned}n(\mathrm{KCl}) &= \frac{m(\mathrm{KCl})}{M(\mathrm{KCl})} \\ &= \frac{195.0\; \rm g}{74.6\; \rm g \cdot mol^{-1}} \approx 2.61\; \em \rm mol\end{aligned}.

\begin{aligned}n(\mathrm{H_2O}) &= \frac{m(\mathrm{H_2O})}{M(\mathrm{H_2O})} \\ &= \frac{215\; \rm g}{18.0\; \rm g \cdot mol^{-1}} \approx 11.9\; \em \rm mol\end{aligned}.

The molar fraction of \rm KCl in this solution would be:

\begin{aligned} X_\mathrm{KCl} &= \frac{n(\mathrm{KCl})}{n(\text{All particles in this soluton})}\\ &= \frac{n(\mathrm{KCl})}{n(\mathrm{KCl}) + n(\mathrm{H_2O})} \\ &\approx \frac{2.61 \; \rm mol}{2.61\; \rm mol + 11.9\; \rm mol} \approx 0.180\end{aligned}.

(Rounded to three significant figures.)

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