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WINSTONCH [101]
3 years ago
14

The enthalpy of formation of CO2 at 25oC is -393.51 kJ/mol. What is the enthalpy of formation at 500 oC?

Chemistry
1 answer:
Kisachek [45]3 years ago
6 0

Answer:

-375.9_KJ/(mol)

Explanation:

H(T2 ) ≈ H(T1)+CPΔT

Specific heat of Carbon is 0.71 J/g K.

At 283.15 the heat capacity is 37.12 J/(mol*K)

Kirchhoff's law

H(T2 ) ≈ H(T1)+CPΔT

Where

H(T1) and H(T2 ) are the heat of formation of CO2 at temperatures T1 and T2

CP is the heat capacity

Thus we have and ΔT is the temperature change

H(T2 ) ≈ -393.51×10^3+CP×(500-25)

= -393.51×10^3+37.12×(500-25)

= -375878 J/(mol)

= -375.9KJ/(mol)

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Internal energy change (ΔU) for the reaction of combustion in the bomb calorimeter is:

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I hope it helps!

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