Rate law for the given 2nd order reaction is:
Rate = k[a]2
Given data:
rate constant k = 0.150 m-1s-1
initial concentration, [a] = 0.250 M
reaction time, t = 5.00 min = 5.00 min * 60 s/s = 300 s
To determine:
Concentration at time t = 300 s i.e. ![[a]_{t}](https://tex.z-dn.net/?f=%5Ba%5D_%7Bt%7D)
Calculations:
The second order rate equation is:
![1/[a]_{t} = kt +1/[a]](https://tex.z-dn.net/?f=1%2F%5Ba%5D_%7Bt%7D%20%3D%20kt%20%2B1%2F%5Ba%5D)
substituting for k,t and [a] we get:
1/[a]t = 0.150 M-1s-1 * 300 s + 1/[0.250]M
1/[a]t = 49 M-1
[a]t = 1/49 M-1 = 0.0204 M
Hence the concentration of 'a' after t = 5min is 0.020 M
Answer:
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<span>As mentioned, the isomerization of cyclopropane to propylene is a first-order process with a half-life of 19 min at 500°c. A first-order reaction kinetic rates means that the rate is constant throughout the reaction.
Thus, the time it takes for the partial pressure of cyclopropane to decrease from 1 atm to 0.125 atm at 500°c is </span><span>57 minutes.</span>
<span>Ionization energy (IE) is the amount of energy required to remove an electron.
If you observe the IEs sequentially, there is a large gap between the 2nd and 3rd. This suggests it is difficult to remove more than 2 two electrons. Elements that lose two electrons to become more stable are found in the Group 2A (2 representing the number of electrons in the outermost valence shell).</span>
