Answer:
Structures of products has been shown below
Explanation:
- In claisen condensation, two ester molecules combines with each other through nucleophilic acyl substitution resulting formation of a
-ketoester. - At first, one ester molecule gets deprotonated in presence of a strong base e.g. NaOEt yielding a carbanion.
- The carbanion then gives nucleophilic acyl substitution reaction with another ester molecule to replace alkoxy group present in ester group
- General reaction mechanism of claisen condensation along with products of given esters are shown below.
Answer:
The second experiment (reversible path) does more work
Explanation:
Step 1:
A piston confines 0.200 mol Ne(g) in 1.20L at 25 degree °C
<em>(a) The gas is allowed to expand through an additional 1.20 L against a constant of 1.00atm</em>
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Irreversible path: w =-Pex*ΔV
⇒ with Pex = 1.00 atm
⇒ with ΔV = 1.20 L
W = -(1.00 atm) * 1.20 L
W = -1.20L*atm *101.325 J /1 L*atm = -121.59 J
<em>(b) The gas is allowed to expand reversibly and isothermally to the same final volume.</em>
<em></em>
W = -nRTln(Vfinal/Vinitial)
⇒ with n = the number of moles = 0.200
⇒ with R = gas constant = 8.3145 J/K*mol
⇒ with T = 298 Kelvin
⇒ with Vfinal/Vinitial = 2.40/1.20 = 2
W = -(0.200mol) * 8.3145 J/K*mol *298K *ln(2.4/1.2)
W = -343.5 J
The second experiment (reversible path) does more work
Mass of sodium :- 23 grams
Mass of Chlorine :- 35.5 grams
Mass of NaCl :- 58.5 grams
mass given :- 25 grams
moles :- 0.432 ( given mass/ ionic mass)
Answer:
<u>5 moles S x (36.02 g S/mole S) = 180.1 grams of S</u>
Explanation:
The periodic table has mass units for every element that can be correlated with the number of atoms of that element. The relationship is known as Avogadro's Number. This number, 6.02x
, is nicknamed the mole, which scientists found to be a lot more catchy, and easier to write than 6.02x. <u>The mole is correlated to the atomic mass of that element.</u> The atomic mass of sulfur, S, is 36.02 AMU, atomic mass units. <u>But it can also be read as 36.02 grams/mole.</u>
<u></u>
<u>This means that 36.02 grams of S contains 1 mole (6.02x</u><u>) of S atoms</u>.
<u></u>
This relationship holds for all the elements. Zinc, Zn, has an atomic mass of 65.38 AMU, so it has a "molar mass" of 65.38 grams/mole. ^5.38 grams of Zn contains 1 mole of Zn atoms.
And so on.
5.0 moles of Sulfur would therefore contain:
(5.0 moles S)*(36.02 grams/mole S) = <u>180.1 grams of S</u>
Note how the units cancel to leaves just grams. The units are extremely helpful in mole calculations to insure the correct mathematical operation is done. To find the number of moles in 70 g of S, for example, we would write:
(70g S)/(36.02 grams S/mole S) = 1.94 moles of S. [<u>Note how the units cancel to leave just moles</u>]
The green and black symbols refer to atoms, that make up the molecule of water, more specifically you can say that the 2 Hydrogen atoms are the black ones found outside, while the central atom, that is also green would be oxygen.
