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Aleksandr-060686 [28]
3 years ago
14

Why is PCI 5 an exception to the octet rule, while PCI3 is not? Please use at least ONE complete content related

Chemistry
1 answer:
Kitty [74]3 years ago
8 0
P has five electrons, three available to share. Since Cl has seven valence electrons, it can take on one more to accomplish an octet. In PCl3, P’s three valence electrons are evenly distributed among the three chlorine atoms. Whereas, in PCl5 there will be two electrons left over, which is why it is an exception to the octet rule.
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A solution contains [Ba2+] = 5.0 × 10−5 M, [Zn2+] = 2.0 × 10−7 M, and [Ag+] = 3.0 × 10−5 M. Sodium oxalate (Na2C2O4) is slowly a
Jet001 [13]

Answer:

BaC₂O₄, then ZnC₂O₄, then Ag₂C₂O₄  

Explanation:

1. Calculate the equilibrium concentrations of oxalate ion

Let [C₂O₄²⁻] = c

(a) Barium oxalate

                 BaC₂O₄ ⇌   Ba²⁺   + C₂O₄²⁻

E/mol·L⁻¹:                   5.0 × 10⁻⁵     c

Ksp = [Ba²⁺][C₂O₄²⁻] = 5.0 × 10⁻⁵c = 1.5 × 10⁻⁸

c = (1.5 × 10⁻⁸)/(5.0 × 10⁻⁵) = 3.0 × 10⁻⁴ mol·L⁻¹

(b) Zinc oxalate

                ZnC₂O₄ ⇌   Zn²⁺   + C₂O₄²⁻

E/mol·L⁻¹:                 2.0 × 10⁻⁷      c

Ksp = [Zn²⁺][C₂O₄²⁻] = 2.0 × 10⁻⁷c = 1.35 × 10⁻⁹

c = (1.35 × 10⁻⁹)/(2.0 × 10⁻⁷) = 6.8 × 10⁻³ mol·L⁻¹

(c) Silver oxalate

                 Ag₂C₂O₄ ⇌   2Ag⁺   +   C₂O₄²⁻  

E/mol·L⁻¹:                      3.0 × 10⁻⁵       c

Ksp = [Ag⁺]²[C₂O₄²⁻] = (3.0× 10⁻⁵)²c = 9.0 × 10⁻¹⁰c = 1.1 × 10⁻¹¹

c = (1.1 × 10⁻¹¹)/(9.0 × 10⁻¹⁰) = 0.012 mol·L⁻¹

2. Decide the order of precipitation

BaC₂O₄ will precipitate when   c > 3.0 × 10⁻⁴ mol·L⁻¹

ZnC₂O₄ will precipitate when   c > 6.8 × 10⁻³ mol·L⁻¹

Ag₂C₂O₄ will precipitate when c > 0.028       mol·L⁻¹

This happens to be the order of increasing concentration of oxalate ion.

The order of precipitation is

BaC₂O₄, then ZnC₂O₄, then Ag₂C₂O₄

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When u add the solution to the chemical's
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Charge: +2

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