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Aleksandr-060686 [28]
3 years ago
14

Why is PCI 5 an exception to the octet rule, while PCI3 is not? Please use at least ONE complete content related

Chemistry
1 answer:
Kitty [74]3 years ago
8 0
P has five electrons, three available to share. Since Cl has seven valence electrons, it can take on one more to accomplish an octet. In PCl3, P’s three valence electrons are evenly distributed among the three chlorine atoms. Whereas, in PCl5 there will be two electrons left over, which is why it is an exception to the octet rule.
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3 0
3 years ago
he rate constant of a certain reaction is known to obey the Arrhenius equation, and to have an activation energy . If the rate c
Leya [2.2K]

The question is incomplete, here is the complete question:

The rate constant of a certain reaction is known to obey the Arrhenius equation, and to have an activation energy Ea = 71.0 kJ/mol . If the rate constant of this reaction is 6.7 M^(-1)*s^(-1) at 244.0 degrees Celsius, what will the rate constant be at 324.0 degrees Celsius?

<u>Answer:</u> The rate constant at 324°C is 61.29M^{-1}s^{-1}

<u>Explanation:</u>

To calculate rate constant at two different temperatures of the reaction, we use Arrhenius equation, which is:

\ln(\frac{K_{324^oC}}{K_{244^oC}})=\frac{E_a}{R}[\frac{1}{T_1}-\frac{1}{T_2}]

where,

K_{244^oC} = equilibrium constant at 244°C = 6.7M^{-1}s^{-1}

K_{324^oC} = equilibrium constant at 324°C = ?

E_a = Activation energy = 71.0 kJ/mol = 71000 J/mol   (Conversion factor:  1 kJ = 1000 J)

R = Gas constant = 8.314 J/mol K

T_1 = initial temperature = 244^oC=[273+244]K=517K

T_2 = final temperature = 324^oC=[273+324]K=597K

Putting values in above equation, we get:

\ln(\frac{K_{324^oC}}{6.7})=\frac{71000J}{8.314J/mol.K}[\frac{1}{517}-\frac{1}{597}]\\\\K_{324^oC}=61.29M^{-1}s^{-1}

Hence, the rate constant at 324°C is 61.29M^{-1}s^{-1}

8 0
4 years ago
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