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EleoNora [17]
3 years ago
7

The iodide ion reacts with hypochlorite ion (the active ingredient in chlorine bleaches) in the following way:

Chemistry
1 answer:
LiRa [457]3 years ago
8 0

Explanation:

(a)  As the given chemical reaction equation is as follows.

           OCl^{-} + I^{-} \rightarrow OI^{-1} + Cl^{-1}

So, when we double the amount of hypochlorite or iodine then the rate of the reaction will also get double. And, this reaction is "first order" with respect to hypochlorite and iodine.

Hence, equation for rate law of reaction will be as follows.

              Rate = K \times [OCl^{-}] \times [l^{-}]

(b)  Since, the rate equation is as follows.

                    Rate = K [OCl^{-}][l^{-}]

Let us assume that ([OCl^{-}] = [l^{-}])

Putting the given values into the above equation as follows.

             1.36 \times 10^{-4} = K \times (1.5 \times 10^{-3})^2

            1.36 \times 10^{-4} = K \times (2.25 \times 10^{-6})

                   K = \frac{1.36 \times 10^{-4}}{2.25 \times 10^{-6}}

                      = 60.4 M^{-1}sec^{-1}

Hence, the value of rate constant for the given reaction is 60.4 M^{-1}sec^{-1} .

(c) Now, we will calculate the rate as follows.

                Rate = K [OCl^{-}][l^{-}]

                         = 60.4 \times (1.8 \times 10^{3}) \times (6.0 \times 10^{4})

                        = 6.52 \times 10^{5}

Therefore, rate when [OCl^{-}] = 1.8 \times 10^{3} M and [I^{-}]= 6.0 \times 10^{4} M is  6.52 \times 10^{5}.

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This is an incomplete question, here is a complete question.

Determine whether each of the following electron configurations is an inert gas, a halogen, an alkali metal, an alkaline earth metal, or a transition metal. Justify your choices.

(a) 1s^22s^22p^63s^23p^5

(b) 1s^22s^22p^63s^23p^63d^74s^2

(c) 1s^22s^22p^63s^23p^63d^{10}4s^24p^6

(d) 1s^22s^22p^63s^23p^63d^4s^1

Answer :

(a) 1s^22s^22p^63s^23p^5   → Halogen

(b) 1s^22s^22p^63s^23p^63d^74s^2    → Transition metal

(c) 1s^22s^22p^63s^23p^63d^{10}4s^24p^6   → Transition metal

(d) 1s^22s^22p^63s^23p^63d^4s^1   → Transition metal

Explanation :

Inert gas : These are the gases which lie in group 18.

Their general electronic configuration is: ns^2np^6 where n is the outermost shell.

Halogen : These are the elements which lie in group 17.

Their general electronic configuration is: ns^2np^5 where n is the outermost shell.

An alkali metal : These are the elements which lie in group 1.

Their general electronic configuration is: ns^1 where n is the outermost shell.

An alkaline earth metal : These are the elements which lie in group 2.

Their general electronic configuration is: ns^2 where n is the outermost shell.

Transition elements : They are the elements which lie between 's' and 'p' block elements. These are the elements which lie in group 3 to 12. The valence electrons of these elements enter d-orbital.

Their general electronic configuration is: (n-1)d^{1-10}ns^{0-2} where n is the outermost shell.

(a) 1s^22s^22p^63s^23p^5

The element having this electronic configuration belongs to the halogen family.

(b) 1s^22s^22p^63s^23p^63d^74s^2

The element having this electronic configuration belongs to the transition family.

(c) 1s^22s^22p^63s^23p^63d^{10}4s^24p^6

The element having this electronic configuration belongs to the transition family.

(d) 1s^22s^22p^63s^23p^63d^4s^1

The element having this electronic configuration belongs to the transition family.

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