Hello Mate!Well, there are
many definitions and descriptions of isolated systems, and
here are some of them:
1.
It can be a physical system which is located very very far from all other systems, so there is absolutely no interaction between them, thus making it isolated.
2.
It can be a thermodynamic system with rigid walls, which prevents mass and energy to pass through.
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Answer:
pH = 10.38
Explanation:
∴ molar mass C9H13N = 135.21 g/mol
∴ pKb = - log Kb = 4.2
⇒ Kb = 6.309 E-5 = [OH-][C9H20O3N+] / [C9H13N]
∴ <em>C</em> sln = (205 mg/L )*(g/1000 mg)*(mol/135.21 g) = 1.516 E-3 M
mass balance:
⇒ <em>C</em> sln = 1.516 E-3 = [C9H20O3N+] + [C9H13N]......(1)
charge balance:
⇒ [C9H20O3N+] + [H3O+] = [OH-]; [H3O+] is neglected, come from water
⇒ [C9H20O3N+] = [OH-].......(2)
(2) in (1):
⇒ [C9H13N] = 1.516 E-3 - [OH-]
replacing in Kb:
⇒ Kb = 6.3096 E-5 = [OH-]² / (1.516 E-3 - [OH-])
⇒ [OH-]² + 6.3096 E-5[OH] - 7.26613 E-8 = 0
⇒ [OH-] = 2.3985 E-4 M
∴ pOH = - Log [OH-]
⇒ pOH = 3.62
⇒ pH = 14 - pOH = 14 - 3.62 = 10.38
Answer:
The equilibrium will be shifted to lift with the formation of a brown gelatinous precipitate of Fe(OH)₃.
Explanation:
- Le Chatelier's principle states that <em>"when any system at equilibrium for is subjected to change in concentration, temperature, volume, or pressure, then the system readjusts itself to counteract the effect of the applied change and a new equilibrium is established that is different from the old equilibrium"</em>.
- The addition of NaOH will result in the formation of Fe(OH)₃ precipitate which has a brown gelatinous precipitate.
- The formation of this precipitate cause removal and decrease of Fe³⁺ ions.
- According to Le Chatelier's principle, the system will be shifted to lift to increase Fe³⁺ concentration and reduce the stress of Fe³⁺ removal and readjust the equilibrium again. So, the [Fe(SCN)²⁺] decreases.
- Increasing [Fe³⁺] will produce a yellow color solution that contains a brown gelatinous precipitate of Fe(OH)₃.
Answer:
solid and liquid state respectively
