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Nookie1986 [14]
3 years ago
13

As the pendulum moves from point 2 to point 3, what happens to its mechanical energy?potential energy is converted to kinetic en

ergy and back again.kinetic energy is converted to potential energy only once.potential energy is converted to kinetic energy only once.kinetic energy is converted to potential energy and back again.
Chemistry
1 answer:
ahrayia [7]3 years ago
3 0

Answer: Potential energy is converted to kinetic energy and back again.

Explanation:At points 1 and 3, the pendulum stops moving, and its mechanical energy is purely potential. At point 2, the pendulum is moving the fastest, and its mechanical energy is purely kinetic. Therefore, as the pendulum moves from point 1 to point 3, its potential energy is first converted to kinetic energy, then back to potential.

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Calculate E ° for the half‑reaction, AgCl ( s ) + e − − ⇀ ↽ − Ag ( s ) + Cl − ( aq ) given that the solubility product constant
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Answer: The value of E^{o} for the half-cell reaction is 0.222 V.

Explanation:

Equation for solubility equilibrium is as follows.

          AgCl(s) \rightleftharpoons Ag^{+}(aq) + Cl^{-}(aq)

Its solubility product will be as follows.

       K_{sp} = [Ag^{+}][Cl^{-}]

Cell reaction for this equation is as follows.

     Ag(s)| AgCl(s)|Cl^{-}(0.1 M)|| Ag^{+}(1.0 M)| Ag(s)

Reduction half-reaction: Ag^{+} + 1e^{-} \rightarrow Ag(s),  E^{o}_{Ag^{+}/Ag} = 0.799 V

Oxidation half-reaction: Ag(s) + Cl^{-}(aq) \rightarrow AgCl(s) + 1e^{-},   E^{o}_{AgCl/Ag} = ?

Cell reaction: Ag^{+}(aq) + Cl^{-}(aq) \rightarrow AgCl(s)

So, for this cell reaction the number of moles of electrons transferred are n = 1.

    Solubility product, K_{sp} = [Ag^{+}][Cl^{-}]

                                               = 1.77 \times 10^{-10}

Therefore, according to the Nernst equation

           E_{cell} = E^{o}_{cell} - \frac{0.0592 V}{n} log \frac{[AgCl]}{[Ag^{+}][Cl^{-}]}

At equilibrium, E_{cell} = 0.00 V

Putting the given values into the above formula as follows.

         E_{cell} = E^{o}_{cell} - \frac{0.0592 V}{n} log \frac{[AgCl]}{[Ag^{+}][Cl^{-}]}

        0.00 = E^{o}_{cell} - \frac{0.0592 V}{1} log \frac{1}{[Ag^{+}][Cl^{-}]}    

       E^{o}_{cell} = \frac{0.0592}{1} log \frac{1}{K_{sp}}

                  = 0.0591 V \times log \frac{1}{1.77 \times 10^{-10}}

                  = 0.577 V

Hence, we will calculate the standard cell potential as follows.

           E^{o}_{cell} = E^{o}_{cathode} - E^{o}_{anode}

       0.577 V = E^{o}_{Ag^{+}/Ag} - E^{o}_{AgCl/Ag}

       0.577 V = 0.799 V - E^{o}_{AgCl/Ag}

       E^{o}_{AgCl/Ag} = 0.222 V

Thus, we can conclude that value of E^{o} for the half-cell reaction is 0.222 V.

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