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Drupady [299]
3 years ago
10

Consider the E2 elimination of 3‑bromopentane with hydroxide. The starting material consists of a chiral carbon with an in plane

bond to bromine pointing to the upper left, an in plane bond to ethyl pointing to the right, a wedged bond to ethyl pointing to the lower left and a dashed bond to hydrogen pointing to the lower left. This reacts with hydroxide to form the product, water and bromide ion. Complete the curved arrow electron-pushing mechanism and draw the structure of the organic product formed.

Chemistry
1 answer:
Tanzania [10]3 years ago
7 0

Answer:

Scheme is attached

Explanation:

When 3‑bromopentane reacts with hydroxide, (Z)-pent-2-ene will produce through E 2 (Z)-pent-2-ene.

Mechanism

Hydroxide ion (OH⁻ ) is a strong nucleophile so it abstract the proton from carbon next to the carbon attached with bromine.

The the carbon next to carbon of bromine gets -ve charge, mean while it shares its electrons with the carbon having bromine and make a double bond.

As bromine  is a good leaving group so it easily gets detached from carbon, so that carbon comes to its normal state.

As a result (Z)-pent-2-ene will produce. we call it Z because mostly trans products will form.

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Answer:

200\; \rm mL of neon \rm Ne\, (g) at 25^{\circ} \rm C and 1\; \rm atm (the second choice) would contain an equal number of gas particles as 200\; \rm mL\! of \rm He \, (g) at 25^{\circ} \rm C\! and 1\; \rm atm\! (assuming that all four gas samples behave like ideal gases.)

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By Avogadro's Law, if the temperature and pressure of two ideal gases is the same, the number of gas particles in each gas would be proportional to the volume of that gas.

All four gas samples in this question share the same temperature and pressure. Hence, if all these gases are ideal gases, the number of gas particles in each sample would be proportional to the volume of that sample. Two of these samples would contain the same number of gas particles if and only if the volume of the two samples is equal to one another.

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