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posledela
3 years ago
7

You have two perfectly insulated cups. One contains water and the other contains an equal volume of another liquid that has half

the density of water and twice the specific heat capacity. You heat the water from 10ºC to 20ºC and other liquid from 80ºC to 90ºC. Compare the amount of heat energy needed to raise the temperature of the other liquid to the amount needed to raise the temperature of the water.
Chemistry
1 answer:
motikmotik3 years ago
4 0

Answer:

The amount of heat absorbed is the same.

Explanation:

Let's label water as substance 1 and the other liquid as substance 2. We know so far that:

  • d_1 = 1 g/cm^3, d_2 = \frac{1}{2} d_1;
  • c_1 = 4.184 \frac{J}{g^oC}, c_2 = 2c_1;
  • \Delta T_1 = \Delta T_2 = 10^oC;
  • V_1 = V_2.

Now we know that the amount of heat absorbed is calculated by the product between specific heat capacity, mass and the change in temperature. Although the initial and final temperatures are not the same for the two substances, the change in temperature is.

Now let's express mass as a product between density and volume:

m_1 = d_1V, m_2 = d_2V

Heat absorbed by the water:

Q_1 = c_1d_1V\Delta T_1

Heat absorbed by the unknown liquid:

Q_2 = c_2d_2V\Delta T_2 = 2c_1\cdot \frac{1}{2} d_1\cdot V\Delta T_1 = c_1d_1V\Delta T_1

Notice now that: Q_1 = Q_2

This means the amount of heat absorbed by each substance is the same.

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This is an incomplete question, here is a complete question and an image is attached below.

The following diagrams represent mixtures of NO(g) and O₂(g). These two substances react as follows:

2NO(g)+O_2(g)\rightarrow 2NO_2(g)

It has been determined experimentally that the rate is second order in NO and first order in O₂.

Based on this fact, which of the following mixtures will have the fastest initial rate?

The mixture (1). The mixture (2). The mixture (3).

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Explanation :

The given chemical reaction is:

2NO(g)+O_2(g)\rightarrow 2NO_2(g)

The rate law expression is:

Rate=k[NO]^2[O_2]

Now we have to determine the number of molecules of NO\text{ and }O_2

In mixture 1 : There are 5 NO and 4 O_2 molecules.

In mixture 2 : There are 7 NO and 2 O_2 molecules.

In mixture 3 : There are 3 NO and 5 O_2 molecules.

Now we have to determine the rate law expression for mixture 1, 2 and 3.

The rate law expression for mixture 1 is:

Rate=k[NO]^2[O_2]

Rate=k(5)^2\times (4)

Rate=k(100)

The rate law expression for mixture 2 is:

Rate=k[NO]^2[O_2]

Rate=k(7)^2\times (2)

Rate=k(98)

The rate law expression for mixture 3 is:

Rate=k[NO]^2[O_2]

Rate=k(3)^2\times (5)

Rate=k(45)

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<em><u>The initial entropy is obtained from the initial pressure and temperature with data from A-6 using interpolation:</u></em>

<em><u>s</u></em><em><u>=</u></em><em><u> </u></em><em><u>8</u></em><em><u>.</u></em><em><u>26</u></em><em><u>5</u></em><em><u>2</u></em><em><u> </u></em><em><u>kJ</u></em><em><u>/</u></em><em><u>kgK</u></em>

<em><u>The final temperature is determined from the entropy and the final pressure with data from A-6 using interpolation:</u></em>

<em><u>T₂ = T₁+</u></em><em><u> </u></em><em><u>T₂ - </u></em><em><u>T₁</u></em><em><u>/</u></em><em><u> </u></em><em><u>8</u></em><em><u>₂</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>8</u></em><em><u>₁</u></em><em><u> </u></em><em><u>(</u></em><em><u> </u></em><em><u>s</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>s</u></em><em><u>₁</u></em><em><u>)</u></em>

<em><u>= </u></em><em><u>(</u></em><em><u>400 +</u></em><em><u> </u></em><em><u>500 - 400</u></em><em><u>/</u></em><em><u>8.3271</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>8.0347</u></em><em><u> </u></em><em><u>(8.2652 - 8</u></em><em><u>)</u></em><em><u>)</u></em>

<em><u>= 478.83°C</u></em>

<em><u>The final enthalpy is determined in the same way:</u></em>

<em><u>h₂= h₁</u></em><em><u> </u></em><em><u>+</u></em><em><u> </u></em><em><u>h₂</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>h₁</u></em><em><u>/</u></em><em><u>s</u></em><em><u>₂</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>s</u></em><em><u>₁</u></em><em><u> </u></em><em><u>( s - s₁)</u></em>

<em><u>= (</u></em><em><u> </u></em><em><u>3275.5</u></em><em><u>+</u></em><em><u> </u></em><em><u>3486.6 </u></em><em><u>-</u></em><em><u> </u></em><em><u>3275.5</u></em><em><u>/</u></em><em><u> </u></em><em><u>8.3271</u></em><em><u> </u></em><em><u>-</u></em><em><u> </u></em><em><u>8.0347</u></em><em><u>)</u></em><em><u> </u></em><em><u>(8.265</u></em><em><u>)</u></em>

<em><u>=</u></em><em><u> </u></em><em><u>3441.91 </u></em><em><u>kJ</u></em><em><u>/</u></em><em><u>kg</u></em>

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