Answer:
The question involves drawing of structures and showing mechanism in which brainly text editor did not support. I made sure I created a pdf file with both the anwsers and explanations in it. The pdf can be found in the attachment below.
Explanation:
Answer:
I think 4 I can't remember
Explanation:
The mechanisms by which amorphous intermediates transform into crystalline materials are poorly understood. Currently, attracting enormous interest is the crystallization of amorphous calcium carbonate, a key intermediary in synthetic, biological, and environmental systems. Here we attempt to unify many contrasting and contradictory studies by investigating this process in detail. We show that amorphous calcium carbonate can dehydrate before crystallizing, both in solution and in air, while thermal analyses and solid-state nuclear magnetic resonance measurements reveal that its water is present in distinct environments. Loss of the final water fraction—comprising less than 15% of the total—then triggers crystallization. The high activation energy of this step suggests that it occurs by partial dissolution/recrystallization, mediated by surface water, and the majority of the particle then crystallizes by a solid-state transformation. Such mechanisms are likely to be widespread in solid-state reactions and their characterization will facilitate greater control over these processes.
Answer:
Partial pressure of dinitrogen tetroxide after equilibrium is reached the second time is 0.82 atm.
Explanation:

Initially
3.0 atm 0
At equilibrium
(3.0-2p) p
Equilibrium partial pressure of 
p = 0.45 atm
The value of equilibrium constant wil be given by :


After addition of 1.5 atm of nitrogen dioxide gas equilibrium reestablishes it self :

After adding 1.5 atm of
:
(2.1+1.5) atm 0.45 atm
At second equilibrium:'
(3.6-2P) (0.45+P)
The expression of equilibrium can be written as:


Solving for P:
P = 0.37 atm
Partial pressure of dinitrogen tetroxide after equilibrium is reached the second time:
= (0.45+P) atm = (0.45 + 0.37 )atm = 0.82 atm
Partial pressure of dinitrogen tetroxide after equilibrium is reached the second time is 0.82 atm.