Answer :
The concentration of 
before any titrant added to our starting material is 0.200 M.
The pH based on this ion concentration is 0.698
Explanation :
First we have to calculate the concentration of before any titrant is added to our starting material.
As we are given:
Concentration of HBr = 0.200 M
As we know that the HBr is a strong acid that dissociates complete to give hydrogen ion and bromide ion 
.
As, 1 M of HBr dissociates to give 1 M of
So, 0.200 M of HBr dissociates to give 0.200 M of
Thus, the concentration of before any titrant added to our starting material is 0.200 M.
Now we have to calculate the pH based on this ion concentration.
pH : It is defined as the negative logarithm of hydrogen ion concentration.
![pH=-\log [H^+]](https://tex.z-dn.net/?f=pH%3D-%5Clog%20%5BH%5E%2B%5D)
Thus, the pH based on this ion concentration is 0.698
Using the exponential decay model; we calculate "k"
We know that "A" is half of A0
A = A0 e^(k× 5050)
A/A0 = e^(5050k)
0.5 = e^(5055k)
In (0.5) = 5055k
-0.69315 = 5055k
k = -0.0001371
To calculate how long it will take to decay to 86% of the original mass
0.86 = e^(-0.0001371t)
In (0.86) = -0.0001371t
-0.150823 = -0.0001371 t
t = 1100 hours
First, we need to get the value of Ka:
when Ka = Kw / Kb
we have Kb = 1.8 x 10^-5
and Kw = 3.99 x 10^-16 so, by substitution:
Ka = (3.99 x 10^-16) / (1.8 x 10^-5) = 2.2 x 10^-11
by using the ICE table :
NH4+ + H2O →NH3 + H+
intial 0.013 0 0
change -X +X +X
Equ (0.013-X) X X
when Ka = [NH3][H+] / [NH4+]
by substitution:
2.2 x 10^-11 = X^2 / (0.013 - X) by solving this equation for X
∴X = 5.35 x 10^-7
∴[H+] = X = 5.35 x 10^-7
∴PH = - ㏒[H+]
= -㏒(5.35 x 10^-7)
= 6.27
Answer:
molecular mass of each substance
molecular mass of each substance
Explanation:
