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mezya [45]
2 years ago
10

A sample of gas X occupies 10 mº at a pressure of 120 kPa.

Chemistry
1 answer:
Mashutka [201]2 years ago
5 0

Answer:

The new pressure of the gas comes out to be 400 KPa.

Explanation:

Initial volume of gas = V = 10\textrm{ m}^{3}

Initial pressure of gas = P = 120 KPa

Final volume of gas = V' = 3\textrm{ m}^{3}

Assuming temperature to be kept constant.

Assuming final pressure of the gas to be P' KPa

PV = P'V' \\120\textrm{ KPa}\times 10\textrm{ m}^{3} = \textrm{P'}\times 3\textrm{ m}^{3} \\\textrm{P'} = 400\textrm{ KPa}

New pressure of gas = 400 KPa

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How can you determine which bond in a structure is more polar without using an electronegativity table?
UkoKoshka [18]
To know this you pretty much do have to kind of memorize a few electronegativities. I don't recall ever getting a table of electronegativities on an exam.
From the structure, you have:

I remember the following electronegativities most because they are fairly patterned:
EN
H
=
2.1
EN
C
=
2.5
EN
N
=
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EN
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=
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EN
F
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4.0
EN
Cl
=
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Notice how carbon through fluorine go in increments of
~
0.5
. I believe Pauling made it that way when he determined electronegativities in the '30s.
Δ
EN
C
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Cl
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1.0
Δ
EN
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H
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Δ
EN
C
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C
=
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Δ
EN
C
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=
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Δ
EN
O
−
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So naturally, with the greatest electronegativity difference of
4.0
−
2.5
=
1.5
, the
C
−
F
bond is most polar, i.e. that bond's electron distribution is the most drawn towards the more electronegative compound as compared to the rest.
When the electron distribution is polarized and drawn towards a more electronegative atom, the less electronegative atom has to move inwards because its nucleus was previously favorably attracted to the electrons from the other atom.
That means generally, the greater the electronegativity difference between two atoms is, the shorter you can expect the bond to be, insofar as the electronegative atom is the same size as another comparable electronegative atom.
However, examining actual data, we would see that on average, in conditions without other bond polarizations occuring:
r
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r
C
−
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≈
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r
C
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r
C
−
F
≈
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r
C
−
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r
O
−
H
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So it is not necessarily the least electronegativity difference that gives the longest bond.
Therefore, you cannot simply consider electronegativity. Examining the radii of the atoms, you should notice that chlorine is the biggest atom in the compound.
r
Cl
≈
79 pm
r
C
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70 pm
r
H
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r
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So assuming the answer is truly
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The
C
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F
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Cl
bond, and potentially the
C
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The shortening of the
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