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2 years ago

How does lanthanide contraction influence the density of period 6 transition element

Chemistry

1 answer:

Kitty [74]2 years ago

6 0

Answer:

For example, the atomic radius of the metal zirconium, Zr, (a period-5 transition element) is 155 pm (empirical value) and that of hafnium, Hf, (the corresponding period-6 element) is 159 pm. ... The increase in mass and the unchanged radii lead to a steep increase in density from 6.51 to 13.35 g/cm3.

Explanation:

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Write a balanced half-reaction for the product that forms at each electrode in the aqueous electrolysis of the following salts:(

likoan [24]

Balanced Half reactions are:

At anode 2 $Cl^{-}$ ==> Cl₂+ $2e^{-}$ + H₂O ==> $ClO^{-}$ + 2 $H^{+}$ + $Cl^{-}$

At Cathode: 2 $H^{+}$ + $2e^{-}$ ==> H₂

Since the question states that you are using an aqueous solution of MnCl₂, so ions will have present are, H₂O, $H^{+}$ , $Mn^{2+}$ and $Cl^{-}$

Now at Anode reaction will occur as given:

2 $Cl^{-}$ ==> Cl₂+ $2e^{-}$ + H₂O ==> $ClO^{-}$ + 2 $H^{+}$ + $Cl^{-}$ (will occur)

At Cathode:

2 $H^{+}$ + $2e^{-}$ ==> H₂ (will occur)

At Cathode:

$Mn^{2+}$ + $2e^{-}$ ==> Mn (This reaction will not occur)

The deposition of solid Mn will not occur because in aqueous solution, $H^{+}$ will be reduced before $Mn^{2+}$ .

The reduction potentials for $H^{+}$ is zero whereas reduction potential for $Mn^{2+}$ is - 1.18V.

The reduction potential of a species is its tendency to gain electrons and get reduced. It is measured in millivolts or volts. Larger positive values of reduction potential are indicative of a greater tendency to get reduced.

To learn more about the half reaction please click on the link brainly.com/question/13186640

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Answer:

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Norma-Jean [14]

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How does lanthanide contraction influence the density of period 6 transition element​

How does lanthanide contraction influence the density of period 6 transition element