How does lanthanide contraction influence the density of period 6 transition element

Chemistry

1 answer:

Kitty [74]2 years ago

6 0

Answer:

For example, the atomic radius of the metal zirconium, Zr, (a period-5 transition element) is 155 pm (empirical value) and that of hafnium, Hf, (the corresponding period-6 element) is 159 pm. ... The increase in mass and the unchanged radii lead to a steep increase in density from 6.51 to 13.35 g/cm3.

Explanation:

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Butane (C4 H10(g), Hf = –125.6 kJ/mol) reacts with oxygen to produce carbon dioxide (CO2 , Hf = –393.5 kJ/mol ) and water (H2 O,

WITCHER [35]

Answer: Enthalpy of combustion (per mole) of $C_4H_{10} (g)$ is -2657.5 kJ

Explanation:

The chemical equation for the combustion of butane follows:

$2C_4H_{10}(g)+4O_2(g)\rightarrow 8CO_2(g)+10H_2O(g)$

The equation for the enthalpy change of the above reaction is:

$\Delta H^o_{rxn}=[(8\times \Delta H^o_f_{CO_2(g)})+(10\times \Delta H^o_f_{H_2O(g)})]-[(1\times \Delta H^o_f_{C_4H_{10}(g)})+(4\times \Delta H^o_f_{O_2(g)})]$

We are given:

$\Delta H^o_f_{(C_4H_{10}(g))}=-125.6kJ/mol\\\Delta H^o_f_{(H_2O(g))}=-241.82kJ/mol\\\Delta H^o_f_{(O_2(g))}=0kJ/mol\\\Delta H^o_f_{(CO_2(g))}=-393.5kJ/mol\\\Delta H^o_{rxn}=?$