Answer:
A. Methanol
B. 2-chloropropan-1-ol
C. 2,2-dichloroethanol
D. 2,2-difluoropropan-1-ol
Explanation:
Primary alcohols are stronger acids than secondary alcohols which are stronger than tertiary alcohols.
This trend is so because of the stability of the alkoxide ion formed(stabilising the base, increases the acidity). A more stabilised alkoxide ion is a weaker conjugate base (dissociation of an acid in water).
By electronic factors, When there are alkyl groups donating electrons, the density of electrons on th O- will increase a d thereby make it less stable.
By stearic factors, More alkyl group bonded to the -OH would mean the bulkier the alkoxide ion which would be harder to stabilise.
Down the group of the periodic table, basicity (metallic character) decreases as we go from F– to Cl– to Br– to I– because that negative charge is being spread out over a larger volume that is electronegativity decreases down the group.
Electronegative atoms give rise to inductive effect and a decrease in indutive effects leads to a decrease in acidity. Therefore an Increasing distance from the -OH group lsads to a decrease in acidity.
From above,
A. Methanol
B. 2-chloropropan-1-ol
C. 2,2-dichloroethanol
D. 2,2-difluoropropan-1-ol
Answer:
0.0432 M H2SO4
Explanation:
First, we want to find the moles of MNaOH used. We know that Molarity x Liters = moles. 0.160M x 0.0210L = 0.00336 moles MNaOH
to find the moles of H2SO4, we can use a mol ratio.
0.00336mol MNaOH x (1Mol H2SO4 /2mol MNaOH)
= 0. 00168 mol H2SO4
I found the mol ratio by looking at the coefficients in front of the molecules I knew(MNaOH) and the molecule I needed to find(H2SO4)
then, to find Molarity, we do mol/Liters
0.00168 mol/ 0.0388L =. 0.0432 M H2SO4
You can convert mL to L by dividing by 1000
the significant figures of this problem is 3, so my final answer will also have 3 sig figs.
Answer:
The order will be:
CCH > CHCH₂ > CH₂CH₃> CH₃
Explanation:
According to Cahn-Ingold-Prelog system we rank the groups based on the atomic number of directly attached atom with the chiral carbon.
For example: between C and H, we rank Carbon first.
If the same atoms are attached for different groups then we prioritized based on the second element with highest atomic number.
For example:
Among CH₃ and C₂H₅, the priority will be given to C₂H₅.
If an atom is double or triple bonded to the directly attached atom then each pi bond is considered to be a new atom.
Hence CH=CH₂ means, that there are two carbons attached to CH carbon.
So the order based on above selection rules will be:
CCH > CHCH₂ > CH₂CH₃> CH₃
