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poizon [28]
3 years ago
14

Like all equilibrium constants, Kw varies somewhat with temperature. Given that Kw is 3.31 × 10−13 at some temperature, compute

the pH of a neutral aqueous solution at that temperature.
Chemistry
1 answer:
Artyom0805 [142]3 years ago
5 0
Since Kw= [H⁺][OH⁻], and the concentration of both substances are the same, the equation is now Kw=[H⁺]²
So,
3.31x10⁻¹³ = [H⁺]²
Take the square root= 5.75x10⁻⁷
Then take the negative log to find the pH:
-log(5.75x10⁻⁷) = 6.25
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Write Lewis structures for the following molecules: (a) ICl, (b) PH3, (c) P4 (each P is bonded to three other P atoms), (d) H2S,
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Answer :  The Lewis-dot structure for the following molecules are shown below.

Explanation :

Lewis-dot structure : It shows the bonding between the atoms of a molecule and it also shows the unpaired electrons present in the molecule.

In the Lewis-dot structure the valance electrons are shown by 'dot'.

Now we have to determine the Lewis-dot structure for the following molecules.

(a) The given molecule is, ICl

As we know that iodine and chlorine have '7' valence electrons.

Therefore, the total number of valence electrons in ICl = 7 + 7 = 14

According to Lewis-dot structure, there are 2 number of bonding electrons and 12 number of non-bonding electrons.

(b) The given molecule is, PH_3

As we know that phosphorous has '5' valence electrons and hydrogen has '1' valence electrons.

Therefore, the total number of valence electrons in PH_3 = 5 + 3(1) = 8

According to Lewis-dot structure, there are 6 number of bonding electrons and 2 number of non-bonding electrons.

(c) The given molecule is, P_4

As we know that phosphorous has '5' valence electrons.

Therefore, the total number of valence electrons in P_4 = 4(5) = 20

According to Lewis-dot structure, there are 6 number of bonding electrons and 14 number of non-bonding electrons.

(d) The given molecule is, H_2S

As we know that sulfur has '6' valence electrons and hydrogen has '1' valence electrons.

Therefore, the total number of valence electrons in H_2S = 6 + 2(1) = 8

According to Lewis-dot structure, there are 4 number of bonding electrons and 4 number of non-bonding electrons.

(e) The given molecule is, N_2H_4

As we know that nitrogen has '5' valence electrons and hydrogen has '1' valence electrons.

Therefore, the total number of valence electrons in N_2H_4 = 2(5) + 4(1) = 14

According to Lewis-dot structure, there are 10 number of bonding electrons and 4 number of non-bonding electrons.

(f) The given molecule is, HClO_3

As we know that chlorine has '7' valence electrons, oxygen has '6' valence electrons and hydrogen has '1' valence electrons.

Therefore, the total number of valence electrons in HClO_3 = 1 + 7 + 3(6) = 26

According to Lewis-dot structure, there are 12 number of bonding electrons and 14 number of non-bonding electrons.

(g) The given molecule is, COBr_2

As we know that bromine has '7' valence electrons, oxygen has '6' valence electrons and carbon has '4' valence electrons.

Therefore, the total number of valence electrons in COBr_2 = 4 + 6 + 2(7) = 24

According to Lewis-dot structure, there are 8 number of bonding electrons and 16 number of non-bonding electrons.

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List and explain the four most important factors that control the relative reactivity of a carbonyl-containing functional group
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Resonance, leaving group, carbonyl carbon delta+, and steric effect is the most crucial variables that affect the relative reactivity of a functional group containing a carbonyl in an addition or substitution process.

Discussion:

1. Carbonyl Carbon Delta+: The carbonyl group becomes more electrophilic and accelerates nucleophilic assault when the carbonyl carbon delta+ is bigger.

2. Resonance: When the carbonyl is transformed into the tetrahedral adduct, it may be lost. Loss of resonance increases the energy of the transition state for this nucleophilic assault because resonance has the function of stabilizing. Therefore, a carbonyl functional group's resistance to nucleophilic attack increases as resonance in the group increases in importance.

3. Leaving group: Tetrahedral adduct fragmentation is encouraged by a better LG.

4. Steric effects: The nucleophilic attack on carbonyl carbon is delayed when sterically impeded.

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2. What if hydrogen were left over?
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Answer: limiting reactant (or limiting reagent): The reactant that determines the amount of product that can be formed in a chemical reaction.

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