Answer:
The order of reaction is 2.
Rate constant is 0.0328 (M s)⁻¹
Explanation:
The rate of a reaction is inversely proportional to the time taken for the reaction.
As we are decreasing the concentration of the reactant the half life is increasing.
a) For zero order reaction: the half life is directly proportional to initial concentration of reactant
b) for first order reaction: the half life is independent of the initial concentration.
c) higher order reaction: The relation between half life and rate of reaction is:
Rate = ![\frac{1}{k[A_{0}]^{(n-1)}}](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7Bk%5BA_%7B0%7D%5D%5E%7B%28n-1%29%7D%7D)
Half life =![K\frac{1}{[A_{0}]^{(n-1)} }](https://tex.z-dn.net/?f=K%5Cfrac%7B1%7D%7B%5BA_%7B0%7D%5D%5E%7B%28n-1%29%7D%20%7D)
![\frac{(halflife_{1})}{(halflife_{2})}=\frac{[A_{2}]^{(n-1)}}{[A_{1}]^{(n-1)} }](https://tex.z-dn.net/?f=%5Cfrac%7B%28halflife_%7B1%7D%29%7D%7B%28halflife_%7B2%7D%29%7D%3D%5Cfrac%7B%5BA_%7B2%7D%5D%5E%7B%28n-1%29%7D%7D%7B%5BA_%7B1%7D%5D%5E%7B%28n-1%29%7D%20%7D)
where n = order of reaction
Putting values
![\frac{109}{231}=\frac{[0.132]^{(n-1)}}{[0.280]^{(n-1)}}](https://tex.z-dn.net/?f=%5Cfrac%7B109%7D%7B231%7D%3D%5Cfrac%7B%5B0.132%5D%5E%7B%28n-1%29%7D%7D%7B%5B0.280%5D%5E%7B%28n-1%29%7D%7D)
Hence n = 2
![halflife=\frac{1}{k[A_{0}]}](https://tex.z-dn.net/?f=halflife%3D%5Cfrac%7B1%7D%7Bk%5BA_%7B0%7D%5D%7D)
Putting values
K = 0.0328
Spectator ion are ions which remain unchanged during chemical equation and does not affect equilibrium
chemical equation for the reaction is as follows
NaSO4 +Babr2 ---> 2 Nabr + BaSO4
ionic equation is as follows
Ba ^+2 + SO^-2 --->BaSO4(s)
therefore the spectator ion are Na+ and Br- ions
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Fe2O3 + 2Al => Al2O3 + 2Fe↓
reaction of changing.
In this type of reaction one element or group of elements from one substance is changed with a single element.
