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KIM [24]
3 years ago
14

Please help me, I’m stuck on this question

Chemistry
1 answer:
zubka84 [21]3 years ago
7 0

Answer:

\large \boxed{\text{0.0820 L$\cdot$atm$\cdot$K$^{-1}$mol}^{-1 }}

Explanation:

To solve this problem, we can use the Ideal Gas Law:

pV = nRT

Data:

p = 3.00 atm

V = 17.4 L

n = 2.00 mol

T = 45 °C

Calculations:

1. Convert the temperature to kelvins

T = (45 + 273.15) K = 318.15 K

2. Calculate the value of R

\begin{array}{rcl}pV & = & nRT\\\text{3.00 atm} \times \text{17.4 L} & = & \text{2.00 mol} \times R \times \text{318.15 K}\\\text{52.2 L$\cdot$atm} & = & 636.30R \text{ K$\cdot$mol}\\R & = & \dfrac{\text{52.2 L$\cdot$atm}}{636.30 \text{ K$\cdot$mol}}\\\\ & = & \textbf{0.0820 L$\cdot$atm$\cdot$K$^{-1}$mol}^{-1} \\\end{array}\\\text{The value of the gas constant R is $\large \boxed{\textbf{0.0820 L$\cdot$atm$\cdot$K$^{-1}$mol}^{-1 }}$}

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So we can calculate the pressure by

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where as,

n = 41.1 g / 44 g/mol = 0.934 mol

Hence P = 0.934 x 0.082 x 298 / 3.4 L = 6.7 atm

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Using the following thermochemical data: 2Y(s) + 6HF(g) → 2YF3(s) + 3H2(g) ΔH° = –1811.0 kJ/mol 2Y(s) + 6HCl(g) → 2YCl3(s) + 3H2
Luba_88 [7]

Answer:

ΔH° =   182.4 kJ/mol

Explanation:

The ΔH wanted is for the reaction :

YF3(s) + 3HCl(g) → YCl3(s) + 3HF(g)

This is a Hess Law problem where e will have to algebraically manipulate the first and second equations , add them together, and arrive at the desired equation above.

Notice if we reverse the first equation and divide it by 2 and add to the the second only divided by two, we will arrive to the desired equation:

2YF3(s) + 3H2(g)  →  2Y(s) + 6HF(g)  ΔH° = 1811.0 kJ/mol (change sign)

dividing by two :

YF3(s) + 3/2H2(g)  →  Y(s) + 3HF(g)     ΔH° =  905.5 kJ/mol  Eq 1

2Y(s) + 6HCl(g) → 2YCl3(s) + 3H2(g) ΔH° = –1446.2 kJ/mol

dividing this one by two,

Y(s) + 3HCl(g) → YCl3(s) + 3/2 H2(g) ΔH° = –1446.2 kJ/mol/2 = - 723.10 kJ/mol Eq 2

Now adding 1 and 2

YF3(s) + 3/2H2(g)  →  Y(s) + 3HF(g)     ΔH° =  905.5 kJ/mol  Eq 1

Y(s) + 3HCl(g) → YCl3(s) + 3/2 H2(g) ΔH° = –1446.2 kJ/mol/2 = - 723.10 kJ/mol Eq 2

________________________________________________________

YF3(s) + 3HCl(g) → YCl3(s) + 3HF(g).   ΔH° =  905.5 + (-723.1) kJ/mol

ΔH° =   182.4 kJ/mol

Notice how the Y(s) and H2 cancel nicely and the coefficients are the right ones.

8 0
4 years ago
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