Answer:
Ethanol is completely miscible due to <u><em>presence</em></u> of Hydrogen bonding.
Ethanethiol is partially miscible due to <u><em>absence</em></u> of Hydrogen Bonding.
Explanation:
The miscibility of liquids depend upon the intermolecular interactions between the two liquids. The stronger the intermolecular interactions the more miscible will be the liquids.
Among the two given examples, Ethanol is more miscible in water because it exhibits hydrogen bonding which is considered the strongest intermolecular interaction. Hydrogen bonding occurs when the hydrogen atom is bonded to more electronegative atoms like Fluorine, Oxygen and Nitrogen. In this way the hydrogen atom gets partial positive charge and the electronegative atom gets partial negative charge. Hence, these partial charges results in attracting the opposite charges on other surrounding atoms.
While, in case of Ethanethiol the hydrogen atom is not bonded to any high electronegative atom hence, there will be no hydrogen bonding and therefore, there will be less interactions between the neighbour atoms.
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Answer:
For any given element, ionization energy increases as subsequent electrons are removed. For example, the energy required to remove an electron from neutral chlorine is 1251 kJ/mol. ... An even sharper increase in ionization energy is witnessed when inner-shell, or core, electrons are removed.
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We have Kc = 4.2 x 10^-2 (given but missing in the question)
and When the balanced equation for this reaction is:
PCl5(g) ↔ PCl3(g) + Cl2(g)
so, according to the Kc formula:
Kc = the concentration of products / the concentration of the reactants
so, to get the concentration of the reactants in equilibrium, the concentration of the products / the concentration of the reactants should equal the Kc value which is given in the question (missing in your question).
So by substitution in Kc formula:
Kc = [PCl3]*[Cl2] / [PCl5]
4.2 x 10^-2 = 0.18 * 0.25 /[PCl5]
∴[PCl5] = 0.18*0.25 / 4.2x10^-2 = 1.07
So the concentration of the reactants in equilibrim = 1.07
The answer is dissolved in water, because in chemistry, (aq) is shorthand for aqueous solution.