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gavmur [86]
3 years ago
14

The radioactive isotope of lead, Pb-209, decays at a rate proportional to the amount present at time t and has a half-life of 3.

3 hours. If 1 gram of this isotope is present initially, how long will it take for 80% of the lead to decay
Chemistry
1 answer:
Marina86 [1]3 years ago
3 0

Answer:

Therefore it will take 7.66 hours for 80% of the lead decay.

Explanation:

The differential equation for decay is

\frac{dA}{dt}= kA

\Rightarrow \frac{dA}{A}=kdt

Integrating both sides

ln A= kt+c₁

\Rightarrow A= e^{kt+c_1}

\Rightarrow A=Ce^{kt}         [e^{c_1}=C]

The initial condition is A(0)= A₀,

\therefore A_0=Ce^{0.k}

\Rightarrow C=A_0

\therefore A=A_0e^{kt}.........(1)

Given that the Pb_{209}  has half life of 3.3 hours.

For half life A=\frac12 A_0 putting this in equation (1)

\frac12A_0=A_0e^{k\times3.3}

\Rightarrow ln(\frac12)= 3.3k     [taking ln both sides, ln \ e^a=a]

\Rightarrow k=\frac{ln \frac12}{3.3}

⇒k= - 0.21

Now A₀= 1 gram, 80%=0.8

and A= (1-0.8)A₀ = (0.2×1) gram = 0.2 gram

Now putting the value of k,A and A₀in the equation (1)

\therefore 0.2=1e^{(-0.21)\times t}

\Rightarrow e^{-0.21t}=0.2

\Rightarrow -0.21t= ln(0. 2)

\Rightarrow t= \frac{ln (0.2)}{-0.21}

⇒ t≈7.66

Therefore it will take 7.66 hours for 80% of the lead decay.

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2.30 × 10⁻⁶ M

Explanation:

Step 1: Given data

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Step 2: Write the reaction for the solution of Mg(OH)₂

Mg(OH)₂(s) ⇄ Mg²⁺(aq) + 2 OH⁻(aq)

Step 3: Calculate the minimum [OH⁻] required to trigger the precipitation of Mg²⁺ as Mg(OH)₂

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Answer : The molecular formula of a compound is, C_6H_5Cl_1

Solution : Given,

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Mass of H = 4.48 g

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Molar mass of H = 1 g/mole

Molar mass of Cl = 35.5 g/mole

Step 1 : convert given masses into moles.

Moles of C = \frac{\text{ given mass of C}}{\text{ molar mass of C}}= \frac{64.03g}{12g/mole}=5.34moles

Moles of H = \frac{\text{ given mass of H}}{\text{ molar mass of H}}= \frac{4.48g}{1g/mole}=4.48moles

Moles of Cl = \frac{\text{ given mass of Cl}}{\text{ molar mass of Cl}}= \frac{31.49g}{35.5g/mole}=0.887moles

Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.

For C = \frac{5.34}{0.887}=6.02\approx 6

For H = \frac{4.48}{0.887}=5.05\approx 5

For Cl = \frac{0.887}{0.887}=1

The ratio of C : H : Cl = 6 : 5 : 1

The mole ratio of the element is represented by subscripts in empirical formula.

The Empirical formula = C_6H_5Cl_1

The empirical formula weight = 6(12) + 5(1) + 1(35.5) = 112.5 gram/eq

Now we have to calculate the molecular formula of the compound.

Formula used :

n=\frac{\text{Molecular formula}}{\text{Empirical formula weight}}

n=\frac{112.5}{112.5}=1

Molecular formula = (C_6H_5Cl_1)_n=(C_6H_5Cl_1)_1=C_6H_5Cl_1

Therefore, the molecular of the compound is, C_6H_5Cl_1

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