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Ilia_Sergeevich [38]
4 years ago
13

In the electrochemical cell using the redox reaction below, the anode half reaction is ________. Sn4+ (aq) + Fe (s) → Sn2+ (aq)

+ Fe2+ (aq) In the electrochemical cell using the redox reaction below, the anode half reaction is ________. (aq) + (s) (aq) + (aq) Fe→Fe2++2e− Sn4+→Sn2++2e− Fe+2e−→Fe2+ Sn4++2e−→Sn2+ Fe+2e−→Sn2+ Request Answer
Chemistry
1 answer:
kenny6666 [7]4 years ago
8 0

Answer:

The anode half reaction is : Fe(s)\rightarrow Fe^{2+}(aq.)+2e^{-}

Explanation:

In electrochemical cell, oxidation occurs in anode and reduction occurs in cathode.

In oxidation, electrons are being released by a species. In reduction, electrons are being consumed by a species.

We can split the given cell reaction into two half-cell reaction such as-

Oxidation (anode): Fe(s)\rightarrow Fe^{2+}(aq.)+2e^{-}

Reduction (cathode): Sn^{4+}(aq.)+2e^{-}\rightarrow Sn^{2+}(aq.)

------------------------------------------------------------------------------------------------------------

overall: Fe(s)+Sn^{4+}(aq.)\rightarrow Fe^{2+}(aq.)+Sn^{2+}(aq.)

So the anode half reaction is : Fe(s)\rightarrow Fe^{2+}(aq.)+2e^{-}

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Write a method that could be used to produce pure crystals of copper chloride from copper oxide and hydrochloric acid.
joja [24]

- Describe how you would make the salt from the reactants.

CuO + 2 HCl → CuCl₂ + H₂O

- Describe how you would purify the salt from the reaction mixture.

Filter the solution and let the product crystallize.

Explanation:

The reaction between copper oxide (CuO) and hydrochloric acid (HCl) will produce copper chloride (CuCl₂) and water:

CuO + 2 HCl → CuCl₂ + H₂O

-Describe how you would make the salt from the reactants

In a beaker which contain cooper oxide add the hydrochloric acid. To avoid working with concentrated hydrochloric acid, the acid may be diluted with water but make sure the add the stoechiometric amount (and a little bit of excess) in respect with the copper oxide.

-Describe how you would purify the salt from the reaction mixture.

Let the reaction proceed and then filter the solution to remove the unreacted cooper oxide.

Let the filtered solution, which contain copper chloride, water and unreacted hydrochloric acid, to stand undisturbed for several days. You may see the crystals growing from the solution. To speed up the process you may reduce the temperature.

Learn more about:

purifying compounds

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4 years ago
3.0 x 10 23 molecules of element Z have a mass of 38 g. What is the mass of 1 mole?
mylen [45]
Does this make sense ?

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What nuclear reaction takes place inside stars?
LiRa [457]
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3 years ago
The enthalpy of reaction changes somewhat with temperature. Suppose we wish to calculate ΔH for a reaction at a temperature T th
Contact [7]

Answer:

-99.8 kJ

Explanation:

We are given the methodology to answer this question, which is basically  Kirchhoff law . We just need to find the heats of formation for the reactants and products and perform the calculations.

The standard heat of reaction is

ΔrHº = ∑ ν x ΔfHº products - ∑ ν x ΔfHº reactants

where ν are the stoichiometric coefficients in the balanced equation, and ΔfHº are the heats of formation at their  standard states.

  Compound                 ΔfHº (kJmol⁻¹)

        SO₂                             -296.8

         O₂                                    0

         SO₃                            -395.8

The balanced chemical equation is

SO₂(g) + ½O₂(g) → SO₃(g)

Thus

Δr, 298K Hº( kJmol⁻¹ ) =  1 x (-395.8) - 1 x (-296.8) = -99.0 kJmol⁻¹

Now the heat capacity of reaction  will be be given in a similar fashion:

Cp rxn = ∑ ν x Cp of products - ∑ ν x Cp of reactants

where ν is as above the stoichiometric coefficient in the balanced chemical equation.

Cprxn ( JK⁻¹mol⁻¹) = 50.7 - ( 39.9 + 1/2 x 29.4 ) = - 3.90

                         = -3.90 JK⁻¹mol⁻¹

Finally Δr,500 K Hº = Δr, 298K Hº +  CprxnΔT

Δr,500 K Hº = - 99 x 10³ J + (-3.90) JK⁻¹ ( 500 - 298 ) K = -99,787.8

                     = -99,787.8 J x 1 kJ/1000 J  = -99.8 kJ

Notice thie difference is relatively small that is why in some problems it is o.k to assume the change in enthalpy is constant over a temperature range, especially if it is a small range of temperatures.

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