Answer:
The order will be:
CCH > CHCH₂ > CH₂CH₃> CH₃
Explanation:
According to Cahn-Ingold-Prelog system we rank the groups based on the atomic number of directly attached atom with the chiral carbon.
For example: between C and H, we rank Carbon first.
If the same atoms are attached for different groups then we prioritized based on the second element with highest atomic number.
For example:
Among CH₃ and C₂H₅, the priority will be given to C₂H₅.
If an atom is double or triple bonded to the directly attached atom then each pi bond is considered to be a new atom.
Hence CH=CH₂ means, that there are two carbons attached to CH carbon.
So the order based on above selection rules will be:
CCH > CHCH₂ > CH₂CH₃> CH₃
<span>1,3-cylohexadiene i synthesized starting from cyclohexane in following 4 steps.
1) Free Radical Substitution Rxn: Halogenation of cyclohexane in the presence of UV yield chlorocyclohexane.
2) Elimination Rxn: Dehydrohalogenation of chlorocyclohexane yields cyclohexene.
3) Halogenation of Cyclohexene (
Electrophillic Addition Rxn) gives 1,2-dihalocyclohexane.
4) Elemination Rxn: When dibromocyclohexane is treated with KOH and heated it gives 1,3-cyclohexadiene as shown below,</span>
Answer:
Specific heat of calcium carbonate(C) = 0.82 (Approx)
Explanation:
Given:
Energy absorbs (q) = 85 J
Change in temperature (Δt) = 34.9 - 21 = 13.9°C
Mass of calcium carbonate = 7.47 g
Find:
Specific heat of calcium carbonate(C)
Computation:
Specific heat of calcium carbonate(C) = q / m(Δt)
Specific heat of calcium carbonate(C) = 85 / (7.47)(13.9)
Specific heat of calcium carbonate(C) = 85 / 103.833
Specific heat of calcium carbonate(C) = 0.8186
Specific heat of calcium carbonate(C) = 0.82 (Approx)
1) Zn(CH₃COO)₂(s) + 2KOH(aq) = Zn(OH)₂(s) + 2CH₃COOK(aq)
Ksp{Zn(OH)₂}=1.2*10⁻¹⁷
2) Zn(CH₃COO)₂(s) + 2NaCN(aq) = Zn(CN)₂(s) + 2CH₃COONa(aq)
Ksp{Zn(CN)₂}=2.6*10⁻¹³
Ksp{Zn(OH)₂}<Ksp{Zn(CN)₂}
Zn(OH)₂ precipitates first