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mafiozo [28]
2 years ago
15

What is the concentration of OH− and pOH in a 0.00072 M solution of Ba(OH)2 at 25 ∘C? Assume complete dissociation.

Chemistry
1 answer:
Mumz [18]2 years ago
3 0

Given :

0.00072 M solution of Ba(OH)_2 at 25^oC .

To Find :

The concentration of OH^-and pOH .

Solution :

1 mole of Ba(OH)_2 gives 2 moles of OH^- ions .

So , 0.00072 M mole of Ba(OH)_2 gives :

[OH^-]=2 \times 0.00072\ M

[OH^-]=0.00144\ M

[OH^-]=1.44\times 10^{-3}\ M

Now , pOH is given by :

pOH=-log[OH^-]\\\\pOH=-log[1.44\times 10^{-3}]\\\\pOH=2.84

Hence , this is the required solution .

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If Ka = 0.54 mM = 1.51x10⁻⁵

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C₄H₈O₂               -------->            C₄H₇O₂⁻          +           H⁺

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E                   0.54x10⁻³(1-x)                      0.54x10⁻³x                0.54x10⁻³x

Recall that x is the percentage degree of dissociation

From the ICE table;

Ka = [C₄H₇O₂⁻] [ H⁺]/[C₄H₈O₂]

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1.51x10⁻⁵ = 0.54x10⁻³x^2/1-x

1.51x10⁻⁵(1-x) = 0.54x10⁻³x^2

1.51x10⁻⁵ - 1.51x10⁻⁵x = 0.54x10⁻³x^2

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x = 0.154 or −0.182

Ignoring the negative result, x = 0.154

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