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mestny [16]
4 years ago
11

2 KClO_2 produces 2 KCl+ 3O_2 when heated. If this reaction produces 82.8 g of KCl how many grams of O2 were produced?

Chemistry
1 answer:
Ad libitum [116K]4 years ago
4 0

Answer:

37.046 grams of oxygen gas were produced.

Explanation:

2KClO_2\rightarrow 2KCl+ 3O_2

Moles of potassium chlorite = \frac{82.2 g}{106.5 g/mol}=0.7718 mol

According to reaction 2 moles of potassium chlorite gives 3 moles of oxygen gas.

Then 0.7718 moles of potassium chlorite will give:

\frac{3}{2}\times 0.7718 mol=1.1577 mol of oxygen gas.

Mass of 1.1577 moles of oxygen gas:

1.1577 mol × 32 g/mol = 37.046 g

37.046 grams of oxygen gas were produced.

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A 0.2 g sample of pyrolusite is analyzed for manganese content as follows. Add 50.0 mL of 0.1 M solution of ferrous ammonium sul
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Answer:

66.7%

Explanation:

The reaction for the titration of the excess ferrous ion is:

  • 5Fe⁺² + MnO₄⁻ + 8H⁺ → 5Fe³⁺ + Mn²⁺ + 4H₂O

We calculate the moles of Fe⁺² from the used moles of KMnO₄:

  • 0.02 M * 15.0 mL = 0.30 mmol KMnO₄
  • 0.3 mmol KMnO₄ * \frac{5mmolFe^{+2}}{1mmolKMnO_4} = 1.5 mmol Fe⁺²

Then we substract those 0.30 mmol from the original amount used:

  • 0.1 M * 50.0 mL = 5.0 mmol Fe⁺²
  • 5.0 - 1.5 = 3.5 mmol Fe⁺²

The reaction between ferrous ammonium sulfate and MnO₂ is:

  • 2Fe⁺² + MnO₂ + 4H⁺ → 2Fe³⁺ + Mn²⁺ + 2H₂O

So we convert those 3.5 mmol Fe⁺² that were used in this reaction to MnO₂ moles:

  • 3.5 mmol Fe⁺²  * \frac{1mmolMnO_2}{2mmolFe^{+2}}= 1.75 mmol MnO₂

Then we convert MnO₂ to Mn₃O₄, using the reaction:

  • 3MnO₂ → Mn₃O₄ + O₂
  • 1.75 mmol MnO₂ * \frac{1mmolMn_3O_4}{3mmolMnO_2} = 0.583 mmol Mn₃O₄

Finally we convert Mn₃O₄ moles to grams:

  • 0.583 mmol Mn₃O₄ * 228.82 mg/mmol = 133.40 mg Mn₃O₄

And calculate the percent

  • 0.2 g = 200 mg
  • 133.40 / 200 * 100% = 66.7%
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