When 0.491 grams of a protein were dissolved in 44 mL of benzene at 24.4 degrees C, the osmotic pressure was found to be 50.9 to
rr. Calculate the molar mass of the protein.
1 answer:
Answer:
4057.85 g/mol
Explanation:
Hello, the numerical procedure is shown in the attached file.
- In this case, since we don't have the density of the protein, we must assume that the volume of the solution is solely given by the benzene's volume, in order to obtain the moles of the solute (protein).
-Van't Hoff factor is assumed to be one.
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Answer:
Here's what I get
Explanation:
(a) Intermediates
The three structures below represent one contributor to the resonance-stabilized intermediate, in which the lone pair electrons on the heteroatom are participating (the + charge on the heteroatoms do not show up very well).
(b) Relative Stabilities
The relative stabilities decrease in the order shown.
N is more basic than O, so NH₂ is the best electron donating group (EDG) and will best stabilize the positive charge in the ring. However, the lone pair electrons on the N in acetanilide are also involved in resonance with the carbonyl group, so they are not as available for stabilization of the ring.
(c) Relative reactivities
The relative reactivities would be
C₆H₅-NH₂ > C₆H₅-OCH₃ > C₆H₅-NHCOCH₃
