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Deffense [45]
3 years ago
11

A hydrogen atom with its electron in the n = 6 energy level emits a photon of IR light. Calculate (a) the change in energy of th

e atom and (b) the wavelength (in Å) of the photon.
Chemistry
1 answer:
geniusboy [140]3 years ago
3 0

Answer:

(a) The change in energy of the atom is --6.0528 X 10⁻²⁰ J

(b) The wavelength of the photon is 32841 Å

Explanation:

E = -kz²/n²

Where;

E is the change in the energy of the atom

k is a constant = 2.179 X 10¹⁸ J

z is the atomic number of hydrogen = 1

n = 6

E = -(1 X 2.179 X 10⁻¹⁸ )/6²

E = -6.0528 X 10⁻²⁰ J

Therefore,the change in energy of the atom is -6.0528 X 10⁻²⁰ J

(b) the wavelength (in Å) of the photon, can be calculated as follows;

E = hc/λ

λ = hc/E

where;

h is Planck's constant = 6.626 X 10⁻³⁴ js

c is the speed of light = 3 X 10⁸ m/s

λ  is the wavelength of the photon

λ  = (6.626 X 10⁻³⁴ X 3 X 10⁸ )/(6.0528 X 10⁻²⁰)

λ  = 3.2841 X 10⁻⁶ m

λ  = 32841 Å

Therefore, the wavelength of the photon is 32841 Å

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3 years ago
Calculate the pKa of lactic acid (CH3CH(OH)COOH) given the following information. 3.005 grams of potassium lactate are added to
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Answer:

\displaystyle \text{p} K_a \approx 3.856

Explanation:

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\displaystyle \begin{aligned} \left[ \text{KC$_3$H_$_5$O$_3$}\right]  & = \frac{3.005\text{ g KC$_3$H_$_5$O$_3$}}{100.\text{ mL}} \cdot \frac{1\text{ mol KC$_3$H_$_5$O$_3$}}{128.17 \text{ g KC$_3$H_$_5$O$_3$}} \cdot \frac{1000\text{ mL}}{1\text{ L}} \\ \\ &= 0.234\text{ M}\end{aligned}

By solubility rules, potassium is completely soluble, so the compound will dissociate completely into potassium and lactate ions. Therefore, [KC₃H₅O₃] = [C₃H₅O₃⁺]. Note that lactate is the conjugate base of lactic acid.

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\displaystyle \begin{aligned}\text{pH} = \text{p}K_a + \log \frac{\left[\text{Base}\right]}{\left[\text{Acid}\right]} \end{aligned}

[Base] = 0.234 M and [Acid] = 0.500 M. We are given that the resulting pH is 3.526. Substitute and solve for p<em>Kₐ</em>:

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\huge{ANSWER}

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