47/3 which could be simplified to 15.6
D) Chlorine is reduced as hydrogen is added whereas Iron is oxidised as Joins with a non hydrogen compound.
According to periodic trends, bismuth has the greatest atomic radius.
We will use this formula for first order:
㏑[A] = - Kt +Ao
when we have t (given)= 30 min = 30 x 60 = 1800 s (we here convert time from min to second.
then we assume that the initial concentration Ao = 1
and the concentration of A (final concentration = 0.25
So by substitution:
㏑(0.25) = - K * 1800 + ㏑(1)
1.39 = K * 1800
∴ K = 0.00077 s^-1 or 7.7 x 10^-4