They're two different clotting pathways that use different factors. Though, the intrinsic and extrinsic pathways come together at factor X and eventually result in fibrinogen (factor I) being converted into a fibrin clot by prothrombin (factor II).
Extrinsic begins with factor VII and intrinsic begins with factor XII
Increasing Substrate Concentration increases the rate of reaction. This is because more substrate molecules will be colliding with enzyme molecules, so more product will be formed.
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