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3 years ago

The following reaction plays a key role in the destruction of ozone In the atmosphere:

Chemistry

1 answer:

lys-0071 [83]3 years ago

6 0

Answer:

19.91 J/K

Explanation:

The entropy is a measure of the randomness of the system, and it intends to increase in nature, thus for a spontaneous reaction ΔS > 0.

The entropy variation can be found by:

ΔS = ∑n*S° products - ∑n*S° reactants

Where n is the coefficient of the substance. The value of S° (standard molar entropy) can be found at a thermodynamic table.

S°, Cl(g) = 165.20 J/mol.K

S°, O3(g) = 238.93 J/mol.K

S°, O2(g) = 205.138 J/mol.K

So:

ΔS = (1*205.138 + 1*218.9) - (1*165.20 + 1*238.93)

ΔS = 19.91 J/K

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The London dispersion force (intermolecular force) is a temporary attractive force between molecules.

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3 years ago

Calculate how many times more soluble Mg(OH)2 is in pure water Based on the given value of the Ksp, 5.61×10−11, calculate the ra

maks197457 [2]

Answer:

molar solubility in water = 2.412 * 10^-4 mol/L

molar solubility of NaOH in 0.130M = 3.32 * 10^-9 mol/L

Mg(OH)2 is a factor 0.73*10^5 more soluble in pure water than in 0.130 M NaOH

Explanation:

The Ksp refers to the partial solubilization of a mostly insoluble salt. This is an equilibrium process.

The equation for the solubilization reaction of Mg(OH)2 can be given as:

Mg(OH)2 (s) → Mg2+ (aq) + 2OH– (aq)

Ksp can then be given as followed:

Ksp = [Mg^2+][OH^–]²

Step 2: Calculate the solubility in water

Mg(OH)2 (s) → Mg2+ (aq) + 2OH– (aq)

The mole ratio Mg^2+ with OH- is 1:2

So there will react X of Mg^2+ and 2X of OH-

The concentration at equilibrium will be XM Mg^2+ and 2X OH-

Ksp = [Mg^2+][OH^–]²

5.61*10^-11 = X * (2X)² = X *4X² = 4X³

X = 2.412 * 10^-4 mol/L = solubility in water

Step 3: Calculate solubility in 0.130 M NaOH

The initial concentration of Mg^2+ = 0 M

The initial concentration of OH- = 0.130 M

The mole ratio Mg^2+ with OH- is 1:2

So there will react X of Mg^2+ and 2X +0.130 for OH-

The concentration at equilibrium will be XM Mg^2+ and 0.130 + 2X OH-

The value of "[OH–] + 2X" is, because the very small value of X, equal to the value of [OH–] .

Let's consider:

[Mg+2] = X

[OH] = 0.130

Ksp = [Mg^2+][OH^–]²

5.61*10^-11 = X *(0.130)²

5.61*10^-11 = X * (0.130)^2

X = 3.32*10^-9 = solubility in 0.130 M NaOH

Step 4: Calculate how many times Mg(OH)2 is better soluble in pure water.

(2.412*10^-4)/ (3.32*10^-9) = 0.73 * 10^5

Mg(OH)2 is a factor 0.73*10^5 more soluble in pure water than in 0.130 M NaOH

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