For parts of the free-response question that require calculations, clearly show the method used and the steps involved in arrivi
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Answer:
The effective nuclear charge for a valence electron in oxygen atom:
Explanation:
Effective nuclear charge is the net nuclear charge experienced by the electron in a given atom. It is always less than the actual charge of the nucleus [Z], due to shielding by electrons in the inner shells.
<em>It is equal to the difference between the actual nuclear charge or the atomic number (Z) and the shielding constant (s). </em>
<u>For an oxygen atom</u>-
Electron configuration: (1s²) (2s² 2p⁴)
<em>The atomic number (actual nuclear charge): </em>Z = 8
The shielding constant (s) for a valence electron can be calculated by using the Slater's rules:
⇒ s = 5 × 0.35 + 2 × 0.85 = 1.75 + 1.7 = 3.45
<u><em>Therefore, the effective nuclear charge for a valence electron in oxygen atom is:</em></u>
<u>Therefore, the effective nuclear charge for a valence electron in oxygen atom:</u>
Answer:
The mean free path = 2.16*10^-6 m
Explanation:
<u>Given:</u>
Pressure of gas P = 100 kPa
Temperature T = 300 K
collision cross section, σ = 2.0*10^-20 m2
Boltzmann constant, k = 1.38*10^-23 J/K
<u>To determine:</u>
The mean free path, λ
<u>Calculation:</u>
The mean free path is related to the collision cross section by the following equation:
where n = number density
Substituting for P, k and T in equation (2) gives:
Next, substituting for n and σ in equation (1) gives: