The difference of the structures of the two isomers are shown in the picture. Generally, cyclic alkanes are much easier to break than straight-chained alkanes. When the molecules are cyclic, they are close to each other, thus lesser bond angles. Because they are closer, repulsion forces could be greater than attractive forces. That is why cyclohexane needs lesser energy of 936 kcal/mol compared to 941 kcal/mol because there is an additional straight-chained methyl substituent to break in methylcyclopentane.
0.01 m 
< 0.03 m 
< 0.04 m urea
As molal concentration rises, so does freezing point depression. It can be expressed mathematically as ΔTf = Kfm.
<h3>What is Colligative Properties ?</h3>
- The concentration of solute particles in a solution, not the composition of the solute, determines a colligative properties .
- Osmotic pressure, boiling point elevation, freezing point depression, and vapor pressure reduction are examples of ligand-like properties.
<h3>What is freezing point depression?</h3>
- When less of another non-volatile material is added, the temperature at which a substance freezes decreases, a process known as Freezing-point depression.
- Examples include combining two solids together, such as contaminants in a finely powdered medicine, salt in water, alcohol in water.
- An significant factor in workplace safety is freezing points.
- If a substance is kept below its freezing point, it may become more or less dangerous.
- The freezing point additionally offers a crucial safety standard for evaluating the impacts of worker exposure to cold conditions.
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P = nRT/V
P = 3.5 x 10^-3 x 0.082 x 298 /0.5
P = 0.171 m Hg
P = 171 mm Hg
hope this helps
