Answer:
[Cr(NH3)6.]C13
Explanation:
Alfred Werner's coordination theory (1893) recognized two kinds of valency;
Primary valency which are nondirectional and secondary valency which are directional.
Hence, the number of counter ions precipitated from a complex depends on the primary valency of the central metal ion in the complex.
We must note that it is only these counter ions that occur outside the coordination sphere that can be precipitated by AgNO3.
If we consider the options carefully, only [Cr(NH3)6.]C13 possess counter ions outside the coordination sphere which can be precipitated when treated with aqueous AgNO3.
Answer: The equilibrium constant for the overall reaction is 
Explanation:
Equilibrium constant is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios.
a) 
![K_a=\frac{[PCl_3]}{[Cl_2]^{\frac{3}{2}}}](https://tex.z-dn.net/?f=K_a%3D%5Cfrac%7B%5BPCl_3%5D%7D%7B%5BCl_2%5D%5E%7B%5Cfrac%7B3%7D%7B2%7D%7D%7D)
b) 
![K_b=\frac{[PCl_5]}{[Cl_2]\times [PCl_3]}](https://tex.z-dn.net/?f=K_b%3D%5Cfrac%7B%5BPCl_5%5D%7D%7B%5BCl_2%5D%5Ctimes%20%5BPCl_3%5D%7D)
For overall reaction on adding a and b we get c
c) 
![K_c=\frac{[PCl_5]}{[Cl_2]^\frac{5}{2}}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BPCl_5%5D%7D%7B%5BCl_2%5D%5E%5Cfrac%7B5%7D%7B2%7D%7D)
![K_c=K_a\times K_b=\frac{[PCl_3]}{[Cl_2]^{\frac{3}{2}}}\times \frac{[PCl_5]}{[Cl_2]\times [PCl_3]}](https://tex.z-dn.net/?f=K_c%3DK_a%5Ctimes%20K_b%3D%5Cfrac%7B%5BPCl_3%5D%7D%7B%5BCl_2%5D%5E%7B%5Cfrac%7B3%7D%7B2%7D%7D%7D%5Ctimes%20%5Cfrac%7B%5BPCl_5%5D%7D%7B%5BCl_2%5D%5Ctimes%20%5BPCl_3%5D%7D)
The equilibrium constant for the overall reaction is
When battery discharge / delivering current the lead at the anode is oxidized
that is ;
pb---->pb+ 2e-
since the lead ions are in presence of aquous sulfate in insoluble lead sulfate precipitate onto the electrode
the overall reaction at the anode is therefore
Pb + SO4^2- ---> PbSO4 + 2e-
