Answer:
n l m
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1 0 0 1s 1 2 2
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2 0 0 2s 1 2
2 1 1,0,-1 2p 3 6 8
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3 0 0 3s 1 2
3 1 1,0,-1 3p 3 6
3 2 2,1,0,-1,-2 3d 5 10 18
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4 0 0 4s 1 2
4 1 1,0,-1 4p 3 6
4 2 2,1,0,-1,-2 4d 5 10
4 3 3,2,1,0,-1,-2,-3 4f 7 14 32
Explanation:
Answer:
-125 kJ
Explanation:
You calculate the energy required to break all the bonds in the reactants. Then you subtract the energy to break all the bonds in the products.
H₂C=CH₂ + H₂ ⟶ H₃C-CH₃
Bonds: 4C-H + 1C=C 1H-H 6C-H + 1C-C
D/kJ·mol⁻¹: 413 612 436 413 347
The formula relating ΔHrxn and bond dissociation energies (D) is
ΔHrxn = Σ(Dreactants) – Σ(Dproducts)
(Note: This is an exception to the rule. All other thermochemical reactions are “products – reactants”. With bond energies, it’s “reactants – products”. The reason comes from the way we define bond energies.)
<em>For the reactant</em>s:
Σ(Dreactants) = 4 × 413 + 1 × 612 + 1 × 436 = 2700 kJ
<em>For the products:</em>
Σ(Dproducts) = 6 × 413 + 1 × 347 = 2825 kJ
<em>For the system</em>
:
ΔHrxn = 2700 - 2825 = -125 kJ
He used a tube of mercury and marked the height of the mercury when placed in an ice bath as 0 degrees celsius, when he placed the tube in a boiling, he marked the height of mercury and called that 100 degrees celsius, he marked it linearly between 0-100 degrees celsius
