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3 years ago

Moseley made revisions to the periodic table

Chemistry

2 answers:

77julia77 [94]3 years ago

8 0

Answer:

yes he did, he restated the period law because mendeleev arrange the elements in order of their atomic mass. Mosley says that since elements of same atom have different atomic masses but no elements of same atom have different atomic number

nalin [4]3 years ago

5 0

Answer:

Moseley made revisions to the periodic table that resolved some of the problems with Mendeleev's version, which accounted for variations from isotopes

Explanation:

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3 years ago

The equilibrium constant Kc for the reaction PCl3(g) + Cl2(g) ⇌ PCl5(g) is 49 at 230°C. If 0.70 mol of PCl3 is added to 0.70 mol

Ymorist [56]

Answer : The correct option is, (B) 0.11 M

Solution :

First we have to calculate the concentration $PCl_3$ and $Cl_2$ .

$\text{Concentration of }PCl_3=\frac{\text{Moles of }PCl_3}{\text{Volume of solution}}$

$\text{Concentration of }PCl_3=\frac{0.70moles}{1.0L}=0.70M$

$\text{Concentration of }Cl_2=\frac{\text{Moles of }Cl_2}{\text{Volume of solution}}$

$\text{Concentration of }Cl_2=\frac{0.70moles}{1.0L}=0.70M$

The given equilibrium reaction is,

$PCl_3(g)+Cl_2(g)\rightleftharpoons PCl_5(g)$

Initially 0.70 0.70 0

At equilibrium (0.70-x) (0.70-x) x

The expression of $K_c$ will be,

$K_c=\frac{[PCl_5]}{[PCl_3][Cl_2]}$

$K_c=\frac{(x)}{(0.70-x)\times (0.70-x)}$

Now put all the given values in the above expression, we get:

$49=\frac{(x)}{(0.70-x)\times (0.70-x)}$

By solving the term x, we get

$x=0.59\text{ and }0.83$

From the values of 'x' we conclude that, x = 0.83 can not more than initial concentration. So, the value of 'x' which is equal to 0.83 is not consider.

Thus, the concentration of $PCl_3$ at equilibrium = (0.70-x) = (0.70-0.59) = 0.11 M

The concentration of $Cl_2$ at equilibrium = (0.70-x) = (0.70-0.59) = 0.11 M