The least massive of all the alkaline earth metals. Who am I?
1 answer:
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Explanation:
Sodium hydroxide completely ionizes in water to produce sodium ions and hydroxide ions. Hydroxide ions are in excess and neutralize all acetic acid added by the following ionic equation:
The mixture would contain
of
and
of
if undergoes no hydrolysis; the solution is of volume
after the mixing. The two species would thus be of concentration
and
, respectively.
Construct a RICE table for the hydrolysis of under a basic aqueous environment (with a negligible hydronium concentration.)
The question supplied the <em>acid</em> dissociation constant for acetic acid
; however, calculating the hydrolysis equilibrium taking place in this basic mixture requires the <em>base</em> dissociation constant
for its conjugate base,
. The following relationship relates the two quantities:
... where the water self-ionization constant under standard conditions. Thus
. By the definition of
:
The rate of disappearance of chlorine gas : 0.2 mol/dm³
<h3>Further explanation</h3>The reaction rate (v) shows the change in the concentration of the substance (changes in addition to concentrations for reaction products or changes in concentration reduction for reactants) per unit time.
For reaction :
The rate reaction :
Reaction for formation CCl₄ :
<em>CH₄+4Cl₂⇒CCl₄+4HCl</em>
<em />
From equation, rate of reaction = rate of formation CCl₄ = 0.05 mol/dm³
Rate of formation of CCl₄ = reaction rate x coefficient of CCCl₄
0.05 mol/dm³ = reaction rate x 1⇒reaction rate = 0.05 mol/dm³
The rate of disappearance of chlorine gas (Cl₂) :
Rate of disappearance of Cl₂ = reaction rate x coefficient of Cl₂
Rate of disappearance of Cl₂ = 0.05 x 4 = 0.2 mol/dm³