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Roman55 [17]
3 years ago
8

Compute the volume percent of graphite, VGr, in a 3.2 wt% C cast iron, assuming that all the carbon exists as the graphite phase

. Assume densities of 7.9 and 2.3 g/cm3 for ferrite and graphite, respectively.
Engineering
1 answer:
Yanka [14]3 years ago
5 0

Answer:

The volume percentage of graphite is 10.197 per cent.

Explanation:

The volume percent of graphite is the ratio of the volume occupied by the graphite phase to the volume occupied by the graphite and ferrite phases. The weight percent in the cast iron is 3.2 wt% (graphite) and 96.8 wt% (ferrite). The volume percentage of graphite is:

\%V_{gr} = \frac{V_{gr}}{V_{gr}+V_{fe}} \times 100\,\%

Where:

V_{gr} - Volume occupied by the graphite phase, measured in cubic centimeters.

V_{fe} - Volume occupied by the graphite phase, measured in cubic centimeters.

The expression is expanded by using the definition of density and subsequently simplified:

\%V_{gr} = \frac{\frac{m_{gr}}{\rho_{gr}} }{\frac{m_{gr}}{\rho_{gr}}+\frac{m_{fe}}{\rho_{fe}}}\times 100\,\%

Where:

m_{fe}, m_{gr} - Masses of the ferrite and graphite phases, measured in grams.

\rho_{fe}, \rho_{gr} - Densities of the ferrite and graphite phases, measured in grams per cubic centimeter.

\%V_{gr} = \frac{1}{1+\frac{\frac{m_{fe}}{\rho_{fe}} }{\frac{m_{gr}}{\rho_{gr}} } }\times 100\,\%

\%V_{gr} = \frac{1}{1 + \left(\frac{\rho_{gr}}{\rho_{fe}} \right)\cdot\left(\frac{m_{fe}}{m_{gr}} \right)} \times 100\,\%

If \rho_{gr} = 2.3\,\frac{g}{cm^{3}}, \rho_{fe} = 7.9\,\frac{g}{cm^{3}}, m_{gr} = 3.2\,g and m_{fe} = 96.8\,g, the volume percentage of graphite is:

\%V_{gr} = \frac{1}{1+\left(\frac{2.3\,\frac{g}{cm^{3}} }{7.9\,\frac{g}{cm^{3}} } \right)\cdot \left(\frac{96.8\,g}{3.2\,g} \right)} \times 100\,\%

\%V_{gr} = 10.197\,\%V

The volume percentage of graphite is 10.197 per cent.

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<u>Explanation:</u>

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Ideal gas law is used to calculate the density:

ρ = \frac{2.2}{2.83 \times 10^{-3} \times 394.3}

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R = \frac{R_{c} }{M} = 8.2 × 10^{-5} / 28.97×10^{-3}

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q=\frac{2.45}{1.97}

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\frac{\Delta P}{L}=\frac{180 \mu}{d_{p}^{2}} \frac{(1-\varepsilon)^{2}}{\varepsilon^{3}} q+\frac{7}{4} \frac{\rho}{d_{p}} \frac{(1-\varepsilon)}{\varepsilon^{3}} q^{2}

\frac{\Delta P}{L}=\frac{180 \times 2.27 \times 10^{-5}}{0.0127^{2}} \frac{(1-0.4)^{2}}{0.4^{3}} 1.24 +\frac{7}{4} \frac{1.97}{0.0127} \frac{(1-0.4)}{0.4^{3}} 1.24^{2}

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Answer:

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W=-\int\limits^a_b {RT(1+\frac{B}{V} +\frac{C}{V^2}\frac{1}{V}  } \, dV

a=v_2\\

b=v_1

Now calculate V1 and V2 at given condition

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W=-\int\limits^a_b {RT(1+\frac{B}{V} +\frac{C}{V^2}\frac{1}{V}  } \, dV

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W=-\int\limits^a_b {P(RT(-1/p^2+0+C')} \, dP

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W=12.59 kJ/mol

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