Answer:
Explanation:
a).
conc of Ca²⁺ =0.0025 M
pCa = -log(0.0025) = 2.6
logK,= 10.65 So lc = 4.47 x 10.
Formation constant of Ca(EDTA)]-z= 4.47 x 10¹⁰ At pH = 11, the fraction of EDTA that exists Y⁻⁴ is 
=0.81
So the Conditional Formation constant= 
=0.81x 4.47 x10¹⁰
=3.62x10¹⁰
b)
At Equivalence point:
Ca²⁺ forms 1:1 complex with EDTA At equivalence point,
Number of moles of Ca²⁺= Number of moles of EDTA Number of moles of Ca²⁺ = M×V = 0.00250 M × 50.00 mL = 0.125 mol
Number of moles of EDTA= 0.125 mol
Volume of EDTA required = moles/Molarity = 0.125 mol / 0.0050 M = 25.00 mL
V e= 25.00 mL
At equivalence point, all Ca²⁺ is converted to [CaY²⁻] complex. So the concentration of Ca²⁺ is determined by the dissociation of [CaY²⁻] complex.
![[CaY^{2-}] = \frac{Initial,moles,of, Ca^{2+}}{Total,Volume} = \frac{0.125mol}{(50.00+25.00)mL} = 0.001667M](https://tex.z-dn.net/?f=%5BCaY%5E%7B2-%7D%5D%20%3D%20%5Cfrac%7BInitial%2Cmoles%2Cof%2C%20Ca%5E%7B2%2B%7D%7D%7BTotal%2CVolume%7D%20%3D%20%5Cfrac%7B0.125mol%7D%7B%2850.00%2B25.00%29mL%7D%20%3D%200.001667M)
Ca²⁺ + Y⁴ ⇄ CaY²⁻
Initial 0 0 0.001667
change +x +x -x
equilibrium x x 0.001667 - x
![{K^'}_f = \frac{[CaY^{2-}]}{[Ca^{2+}][Y^4]}=\frac{0.001667-x}{x.x} =\frac{0.001667-x}{x^2}\\\\x^2 = \frac{0.001667-x}{{K^'}_f}\\ \\](https://tex.z-dn.net/?f=%7BK%5E%27%7D_f%20%3D%20%5Cfrac%7B%5BCaY%5E%7B2-%7D%5D%7D%7B%5BCa%5E%7B2%2B%7D%5D%5BY%5E4%5D%7D%3D%5Cfrac%7B0.001667-x%7D%7Bx.x%7D%20%3D%5Cfrac%7B0.001667-x%7D%7Bx%5E2%7D%5C%5C%5C%5Cx%5E2%20%3D%20%5Cfrac%7B0.001667-x%7D%7B%7BK%5E%27%7D_f%7D%5C%5C%20%5C%5C)
x = 2.15×10⁻⁷
[Ca+2] = 2.15x10⁻⁷ M
pca = —log(2 15x101= 6.7
The amount of space would be consider matter
The potential energy of the ball is 8 J.
<h3>What is mechanical energy?</h3>
Mechanical energy is given as the energy possessed by an object to do work. It is given as the sum of the kinetic energy and potential energy.
Mechanical energy = Kinetic energy + Potential energy
The given ball has:
- Mechanical energy = 25 J
- Kinetic energy = 17 J
The potential energy is given as;
25 J = 17 J + Potential energy
Potential energy = 25 J - 17 J
Potential energy = 8 J
The potential energy of the ball is 8 J.
Learn more about potential energy, here:
brainly.com/question/24284560
#SPJ4
<u>Given:</u>
Moles of gas, n = 1.50 moles
Volume of cylinder, V = 15.0 L
Initial temperature, T1 = 100 C = (100 + 273)K = 373 K
Final temperature, T2 = 150 C = (150+273)K = 423 K
<u>To determine:</u>
The pressure ratio
<u>Explanation:</u>
Based on ideal gas law:
PV = nRT
P= pressure; V = volume; n = moles; R = gas constant and T = temperature
under constant n and V we have:
P/T = constant
(or) P1/P2 = T1/T2 ---------------Gay Lussac's law
where P1 and P2 are the initial and final pressures respectively
substituting for T1 and T2 we get:
P1/P2 = 373/423 = 0.882
Thus, the ratio of P2/P1 = 1.13
Ans: The pressure ratio is 1.13
