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2 answers:
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Answer:
pH after the addition of 10 ml NaOH = 4.81
pH after the addition of 20.1 ml NaOH = 8.76
pH after the addition of 25 ml NaOH = 8.78
Explanation:
(1)
Moles of butanoic acid initially present = 0.1 x 20 = 2 m moles = 2 x 10⁻³ moles,
Moles of NaOH added = 10 x 0.1 = 1 x 10⁻³ moles
CH₃CH₂CH₂COOH + NaOH ⇄ CH₃CH₂CH₂COONa + H₂O
Initial conc. 2 x 10⁻³ 1 x 10⁻³ 0
Equilibrium 1 x 10⁻³ 0 1 x 10⁻³
Final volume = 20 + 10 = 30 ml = 0.03 lit
So final concentration of Acid =
Final concentration of conjugate base [CH₃CH₂CH₂COONa]
Since a buffer solution is formed which contains the weak butanoic acid and conjugate base of that acid .
Using Henderson Hasselbalch equation to find the pH
