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Elina [12.6K]
4 years ago
7

Balance the redox reaction below in acidic solution. pbo2(s) + i-(aq) pb2+(aq) + i2(s) when balanced what is the sum of all the

coefficients?
Chemistry
1 answer:
chubhunter [2.5K]4 years ago
6 0
Two Half Cell reactions are as,

Reduction:                   PbO₂  +  2e⁻   →     Pb²⁺  

As it is acidic medium reaction, so add H⁺ on reactant side as it has more number of oxygen atoms and add H₂O on product side, and balance tehe elements, So,
                             4 H⁺     +   PbO₂  +  2e⁻   →     Pb²⁺   +    2 H₂O      (1)

Oxidation:                        I⁻     →     I₂   +  1e⁻

Balance Number of elements along with electrons,

                                        2 I⁻     →     I₂   +  2e⁻                                    (2)

Compare eq. 1 and 2,

                             4 H⁺     +   PbO₂  +  2e⁻   →     Pb²⁺   +    2 H₂O

                                                           2 I⁻     →     I₂   +  2e⁻ 
                            ⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻⁻
                            PbO₂  +  2 I⁻  +  4 H⁺     →     Pb²⁺  +  I₂  +  2H₂O


                                   Number of Coefficients  =  11
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